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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Contributions to mineralogy and petrology 114 (1993), S. 160-170 
    ISSN: 1432-0967
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie
    Notizen: Abstract A suite of granites from the Hercynian batholith of Sardinia (Italy) was analysed for cesium and 37 other major and trace elements.Factor analysis was used to identify inter-element associations in this set of data. Cesium is shown to be closely associated with tin, lithium and rubidium, and less closely with beryllium and thallium, but it shows no correlation with any of the major elements. The role of crystal fractionation, magma mixing, and the process of partial melting in the magmatic source region are examined as possible controls of Cs distribution. The pattern of element associations revealed by factor analysis eliminates crystal fractionation and magma mixing as the main cause of magmatic variation. The variation in Cs is considered to be primary in origin, i.e. it originated in the magmatic source region. The relationship between Cs and other elements was mainly determined by the relative proportions of mica and feldspar entering the melt during anatexis.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of radioanalytical and nuclear chemistry 233 (1998), S. 63-67 
    ISSN: 1588-2780
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik
    Notizen: Abstract The use of paint as a coating for toys intended for sale on the European market is controlled by a European Standard (EN 71-3: 1994-European Standard for the Safety of Toys, Part 3—Migration of Elements). This work is the result of a preliminary study organised by the European Commission to produce a new paint reference material which can be used to validate the test methods given in the European Standard. The migration of elements from painted panels and comminuted paint produced by the Laboratory of the Government Chemist, (U.K.) was studied. Several methods were used in this certification exercise and this work reports the recults of neutron activation analysis and inductively coupled plasma mass spectrometry to determine the migration of As, Ba, Cd, Cr, Hg, Pb, Se and Sb into a simulated stomach environment. Replicate extracts obtained from paint samples gave a precision of within 10% for most elements by both analytical techniques for the paint panels and for the comminuted paint sample. This preliminary study has shown that the standard method can provide reproducible results for each of the paint materials studied and indicates that the study should be continued to produce a fully certified paint reference material.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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