In:
Angewandte Chemie International Edition, Wiley, Vol. 60, No. 37 ( 2021-09-06), p. 20200-20203
Abstract:
Aqueous reactions between organic peroxides and SO 2 are of intense interest in atmospheric science because of their ubiquitous implications for sulfate formation in secondary aerosols. However, the relative yields of the reaction products (inorganic vs. organic sulfates) remain controversial (i.e., 90 % vs. 40–70 % for inorganic sulfate) due in part to the lack of understanding of the underlying reaction mechanisms. Here, our computational results suggest that the reactions of HSO 3 − (dissolved SO 2 ) with organic peroxides are initiated on the surface of water nanodroplets and then proceed under two reaction pathways, in which the S atom of HSO 3 − attacks either the O1 or O2 atom of the peroxide group ‐O(O2)O(O1)H, leading to the formation of inorganic and organic sulfates, respectively. Notably, we find that thse reaction initiated by O1 atom exhibits a relatively low energy barrier and high reaction rate, which favours the formation of inorganic sulfate.
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.202105416
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7
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