In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2004, No. 7 ( 2004-04), p. 1385-1388
Abstract:
A novel two‐dimensional organic−inorganic hybrid vanadate complex [{Co III (phen) 2 } 2 V 8 O 23 ] has been hydrothermally synthesized and characterized by elemental analyses, IR spectroscopy, XPS spectroscopy, TG analysis and single‐crystal X‐ray diffraction. The single‐crystal X‐ray diffraction analysis reveals that compound 1 contains an unprecedented neutral 2D framework constructed of 4,10,12‐net sheets. To the best of our knowledge, compound 1 represents the first example of 2D layered vanadium oxide complex constructed of 4,10,12‐net sheets. Furthermore, the title compound consists of left‐handed and right‐handed helical chains, which are further interconnected to form the double‐helical chains. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2004:7
DOI:
10.1002/ejic.200300534
Language:
English
Publisher:
Wiley
Publication Date:
2004
detail.hit.zdb_id:
1475009-0
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