In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 78, No. 5 ( 2022-05-01), p. 477-480
Abstract:
The title compound, C 33 H 33 N 3 , is a carbazolophane, which is a cyclophane composed of two carbazole fragments. It has a planar chirality but crystallizes as a racemate in the space group P -1. The molecule adopts an anti -configuration, in which two carbazole fragments are partially overlapped. Both carbazole ring systems are slightly bent, with the C atoms at 3-positions showing the largest deviations from the mean planes. The dihedral angle between two carbazole fragments is 5.19 (3)°, allowing an intramolecular slipped π–π interaction [ Cg ... Cg = 3.2514 (8) Å]. In the crystal, the molecules are linked via intermolecular C—H...N hydrogen bonds and C—H...π interactions into a network sheet parallel to the ab plane. The molecules of different sheets form other C—H...π interactions, thus forming a three-dimensional network.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S2056989022003383
DOI:
10.1107/S2056989022003383/yk2167sup1.cif
DOI:
10.1107/S2056989022003383/yk2167Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2022
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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