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  • 1
    In: Food Science & Nutrition, Wiley, Vol. 10, No. 3 ( 2022-03), p. 822-832
    Abstract: A novel heteropolysaccharide, named cress water soluble polysaccharide (CWSP), was purified from Lepidium sativum seeds. Antioxidant activities and functional properties were characterized thermally using thermal gravimetric analysis (TGA), and the differential scanning calorimeter (DSC) results of CWSP were evaluated. The total antioxidant capacity and the metal chelating activities of CWSP at 3 mg/ml were equivalent to 116.34 µg ascorbic acid and 62.57%, respectively. As for the CWSP that was used for the production of cakes, it was thermally stable, and it presented high water (WHC) and oil holding (OHC) capacities and good emulsion properties. The samples were prepared with different levels of CWSP (0.1. 0.3, and 0.5%) and analyzed during 15 days of storage at room temperature. The obtained results indicated that the addition of CWSP had a significant effect on the texture profile, leading to the increase in all parameters in terms of hardness, springiness, cohesiveness, adhesiveness, and chewiness. Moreover, the reformulation samples presented higher a* and lower L* and b* than the control sample. The sensory evaluation showed that the formulation of cake with 0.3% of CWSP was the most acceptable. Therefore, CWSP was shown to be a new alternative for improving the quality attributes, indicating potent antioxidant activities on the shelf life during the storage of bakery foods.
    Type of Medium: Online Resource
    ISSN: 2048-7177 , 2048-7177
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2703010-6
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  • 2
    In: Polymer Composites, Wiley, Vol. 42, No. 5 ( 2021-05), p. 2492-2501
    Abstract: The morphological, thermal and electrical properties of nanocomposites based on polypropylene (PP) filled with 2 wt% and 6 wt% of organo‐clay montmorillonite (MMT) were studied in this research. X‐ray diffraction show an increase of the inter‐lamellar distance indicating that PP chains have been well intercalated in the galleries of the montmorillonite. Transmission electron microscopy images show a good dispersion of the nanoclay with orientation parallel to the film surface. Moreover, it is also noted that an improvement in PP/MMT nanoclay interfacial adhesion with better orientation is achieved in PP2% compared to PP6%. The study of the real, ε ′ , and imaginary, ε ″ , parts of the complex permittivity shows the presence of the α c relaxation process and an interfacial polarization only in the cases of the PP2% and PP6% nanocomposites. We note a change in the activation energy value E a (MWS) in regard to the variation of the dielectric strength parameter ∆ ε (MWS). The PP2% nanocomposite has the highest value of E a =1.027 eV, which agrees with the lowest value of ∆ ε (MWS), then decreases with PP6% to the value E a =0.962 eV. This difference reflects the highest interactions between the reinforcement (MMT nanoclay) and the matrix (PP) in the case of PP2% nanocomposite proving a good adhesion between PP matrix and MMT nanoclay and more rigid interface compared to the nanocomposite PP6%.
    Type of Medium: Online Resource
    ISSN: 0272-8397 , 1548-0569
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2021
    detail.hit.zdb_id: 1475935-4
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  • 3
    In: Polymer Composites, Wiley, Vol. 41, No. 11 ( 2020-11), p. 4907-4919
    Abstract: The dielectric properties of fluorinated cyano copolymer poly(acrylonitrile‐ co ‐2,2,2‐Trifluoroethyl methacrylate) (poly[AN‐ co ‐MATRIF]), reinforced with a natural Moroccan beidellite nanoclay organomodified with cetyltrimethylammonium bromide were studied. The effect of varying nanofillers loadings (1 wt%, 2 wt%, 3 wt%, and 5 wt%) on the molecular dynamics was investigated using broadband dielectric spectroscopy from 10 −1 to 10 6 Hz and temperatures ranging between 30°C to 100°C. For the copolymer matrix, the real ( ε ′ ) and imaginary parts ( ε ′′ ) of the dielectric permittivity curves revealed three dielectric processes: the secondary β , the primary α and an ionic conduction phenomenon. Furthermore, incorporating of organomodified nanoclay, generated an additional relaxation process known as the Maxwell‐Wagner‐Sillars (MWS) interfacial polarization. The interface properties were investigated through the calculation of the strength parameters ∆ε MWS using the WinFit impedance analysis software. At the range of 3 wt% of load, the orientation of the dipolar groups is reduced, caused by the high interaction and the strong adhesion involving the poly(AN‐ co ‐MATRIF) matrix and beidellite nanoclay. The part of nanoinclusions participating in the particle‐polymer interaction is increased, forming a rigid polymer/clay interfaces. The evaluated parameters confirm that a weight ratio of 3% of organomodified nanoclay is recommended to obtain a most performing nanocomposite that can serve in several applications such as fuel cells, lithium ion batteries, and photovoltaics.
    Type of Medium: Online Resource
    ISSN: 0272-8397 , 1548-0569
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 1475935-4
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  • 4
    Online Resource
    Online Resource
    IOP Publishing ; 2023
    In:  Journal of Physics D: Applied Physics Vol. 56, No. 40 ( 2023-10-05), p. 405301-
    In: Journal of Physics D: Applied Physics, IOP Publishing, Vol. 56, No. 40 ( 2023-10-05), p. 405301-
    Abstract: The effects of isothermal conditions on the charge transport processes and electron emission properties of polybutylene succinate (PBS) nanocomposites with different nanoclay content are investigated. The temperature range used (20 °C–80 °C) is close to the working conditions of materials used in many applications (insulation, sensors). These effects are highlighted using an appropriate device placed in a scanning electron microscope, allowing measurement of induced current in an electron-irradiated specimen. The experimental results show that the rise in temperature involves a decrease in the charging ability and an increase in the conductivity of PBS nanocomposites. The mobility of charge carriers and its thermal dependency deduced during the discharge step were found to be lower for the nanocomposites. A qualitative analysis, expressed to understand these observations, is based on the determination of the electron trap energy distribution (i.e. density of occupied states). Secondary electron emission yield decreased with increasing temperature. The results help us envision a new class of insulators with improved electrical performance. The operating thermal stress, combined with the absence of trapped charges, allows a reduction of electrical and thermal aging and consequently ensures the long-term reliability of the insulators (for instance under High Voltage).
    Type of Medium: Online Resource
    ISSN: 0022-3727 , 1361-6463
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 209221-9
    detail.hit.zdb_id: 1472948-9
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