In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 65, No. 6 ( 2009-06-01), p. m643-m644
Abstract:
In the title compound, [Yb(C 24 H 40 BN 6 ) 2 ]·C 7 H 8 , the Yb atom is coordinated by two tris(3- tert -butyl-5-methylpyrazol-1-yl)hydridoborate [Tp t Bu,Me ] ligands. One ligand binds in the κ 3 mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of the pyrazolyl rings and the H atom attached to the central B via an agostic-type interaction through the B—H group of the second Tp t Bu,Me ligand, giving an overall distorted octahedral geometry. One of the tert -butyl groups is disordered over two sites, with occupancies of 0.65 and 0.35.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536809017152
DOI:
10.1107/S1600536809017152/lh2812sup1.cif
DOI:
10.1107/S1600536809017152/lh2812sup0.html
DOI:
10.1107/S1600536809017152/lh2812Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2009
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
Permalink