In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 7 ( 2014-07-01), p. m242-m243
Abstract:
The crystal structure of the title compound, [Re 6 Se 8 {NCC(CH 3 ) 3 }(Et 3 P) 5 ](SbF 6 ) 2 ·NCC(CH 3 ) 3 , contains a face-capped octahedral [Re 6 (μ 3 -Se) 8 ] 2+ cluster core. The pseudo-centrosymmetric [Re 6 Se 8 ] 2+ cluster core is bonded through the Re atoms to five triethylphosphane ligands and one trimethylacetonitrile ligand. No significant interactions are observed between the cationic cluster, the SbF 6 − anions and the trimethylacetonitrile solvent molecule.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814011982
DOI:
10.1107/S1600536814011982/gk2611sup1.cif
DOI:
10.1107/S1600536814011982/gk2611Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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