In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 51, No. 6 ( 1996-6-1), p. 757-764
Kurzfassung:
A series of three N-(pyrrol-l-yl)salicylaldim ines 1-3 has been prepared an d characterized. Their metal chelate complexes with Cu, Ni and Co are described. The molecular structures of bis[N-(pyrrol-l-yl)salicylaldim inato]copper(lI) la, bis{N-[3-(pyrrol-l-yl)propyl] - salicylaldiminato}nickel(II) 2b and tris{N-[3-(pyrrol-l-yl)propyl]salicylaldiminato}cobalt(III) 2d were determined by X-ray structure analysis. The chelates with tetracoordinated copper and nickel show a square planar coordination with the characteristic trans configuration. The chelate with hexacoordinated cobalt has a meridional coordination sphere. The complexes have also been investigated by X-ray absorption spectroscopy (X̲-ray A̲bsorption N̲ear E̲dge S̲tructure, XANES) at the K edges of the 3d metals. Analyzing the relative intensities of the Is → 3d prepeak and the K edges of the line shape, it was possible to distinguish between planar, tetrahedral and octahedral coordination of the chelates
Materialart:
Online-Ressource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1996-0601
Sprache:
Englisch
Verlag:
Walter de Gruyter GmbH
Publikationsdatum:
1996
ZDB Id:
2078109-X
ZDB Id:
124635-5
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