In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 640, No. 15 ( 2014-12), p. 3118-3126
Abstract:
The cathode materials LiNi 0.5 Mn 1.5 O 4 and LiNi 0.4 Fe 0.2 Mn 1.4 O 4 were synthesized using a citric acid‐assisted sol‐gel method with a final calcination temperature of 1000 °C. An impurity phase exists in LiNi 0.5 Mn 1.5 O 4 powders, which can be eliminated by substituting some of the Ni 2+ and Mn 4+ ions with Fe 3+ . The substitution of Fe into the spinel structure was confirmed by NMR and Mössbauer spectroscopy. The initial capacity of LiNi 0.4 Fe 0.2 Mn 1.4 O 4 powder synthesized at 1000 °C (LNFMO) is slightly higher than that of LiNi 0.5 Mn 1.5 O 4 powder synthesized at 1000 °C (LNMO). Additionally, its capacity retention of 92 % at room temperature after 300 cycles at C/2 charging‐discharging rate between 3.5–5.0 V is higher than that of the Fe‐free sample (79.5 %) under same conditions which could arise from the difference in their cycling mechanisms. In order to understand the structural evolution of these materials during electrochemical cycling, in situ studies under real operating conditions were performed. Measurements of initial powders in capillaries and in situ experiments during the first galvanostatic cycle were carried out by high resolution powder diffraction using synchrotron radiation.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v640.15
DOI:
10.1002/zaac.201400247
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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