In:
Chemie Ingenieur Technik, Wiley, Vol. 89, No. 10 ( 2017-10), p. 1350-1359
Abstract:
A high‐speed pulse reactor setup for the study of chemical reactions which are catalyzed by a fixed bed is described. The benefits of this method compared to stationary‐state measurements are demonstrated using the example of ethylene epoxidation on elemental silver. It is shown that the intrinsic catalyst reactivity depends strongly on oxygen loading and has a pronounced maximum for a loading of about 50 %. In contrast, the selectivity is independent thereof. The relevance of the method for research in catalysis and its relation to the well‐established temporal analysis of products approach are illustrated and discussed.
Type of Medium:
Online Resource
ISSN:
0009-286X
,
1522-2640
DOI:
10.1002/cite.201700071
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
215592-8
detail.hit.zdb_id:
2035041-7
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