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  • 1
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 382, No. 6675 ( 2023-12-08)
    Abstract: Anthropogenic carbon dioxide (CO 2 ) emissions have driven an increase in the global atmospheric CO 2 concentration from 280 parts per million (ppm) before industrialization to an annual average of 419 ppm in 2022, corresponding to an increase in global mean surface temperature (GMST) of 1.1°C over the same period. If global CO 2 emissions continue to rise, atmospheric CO 2 could exceed 800 ppm by the year 2100. This begs the question of where our climate is headed. The geologic record is replete with both brief and extended intervals of CO 2 concentration higher than today and thus provides opportunities to project the response of the future climate system to increasing CO 2 . For example, it has been estimated that global surface temperature 50 million years ago (Ma) was ~12°C higher than today, in tandem with atmospheric CO 2 concentrations some 500 ppm higher (i.e., more than doubled) than present-day values. Consistent with these estimates, Antarctica and Greenland were free of ice at that time. However, reconstructing these values prior to direct instrumental measurements requires the use of paleoproxies—measurable properties of geological archives that are closely, but only indirectly, related to the parameter in question (e.g., temperature, CO 2 ). To date, at least eight different proxies from both terrestrial and marine archives have been developed and applied to reconstruct paleo-CO 2 , but their underlying assumptions have been revised over time, and published reconstructions are not always consistent. This uncertainty complicates quantification of the climate responses to the ongoing rise of atmospheric CO 2 concentrations. RATIONALE Although earlier studies have compiled published paleo-CO 2 estimates, those studies typically applied only limited proxy vetting, included estimates that were made before the proxies were sufficiently validated, and/or focused on only a subset of available proxy data. The international consortium of the Cenozoic CO 2 Proxy Integration Project (CenCO 2 PIP) has undertaken a 7-year effort to document, evaluate, and synthesize published paleo-CO 2 records from all available archives, spanning the past 66 million years. The most reliable CO 2 estimates were identified, some records were recalculated to conform with the latest proxy understanding, age models were updated where necessary and possible, and data were categorized according to the community’s level of confidence in each estimate. The highest-rated data were eventually combined into a reconstruction of the Cenozoic history of atmospheric CO 2 . RESULTS The resulting reconstruction illustrates a more quantitatively robust relationship between CO 2 and global surface temperature, yielding greater clarity and confidence than previous syntheses. The new record suggests that early Cenozoic “hothouse” CO 2 concentrations peaked around 1600 ppm at ~51 Ma. Near 33.9 Ma, the onset of continent-wide Antarctic glaciation coincided with an atmospheric CO 2 concentration of 720 ppm. By ~32 Ma, atmospheric CO 2 had dropped to 550 ppm, and this value coincided with the onset of radiation in plants with carbon-concentrating mechanisms that populate grasslands and deserts today. CO 2 remained below this threshold for the remainder of the Cenozoic and continued its long-term decrease toward the present. Along this trajectory, the middle Miocene (~16 Ma) marks the last time that CO 2 concentrations were consistently higher than at present; Greenland was not yet glaciated at that time, and independent estimates suggest that sea level was some 50 m higher than today. Values eventually dropped below 270 ppm at the Plio-Pleistocene boundary (2.6 Ma), when Earth approached our current “icehouse” state of bipolar glaciation. This and other climatic implications of the revised CO 2 curve, including the evolution of the cryosphere, flora, and fauna, along with the cross-disciplinary data assessment process, are detailed in the full online article. CONCLUSION This community-vetted CO 2 synthesis represents the most reliable data available to date and a means to improve our understanding of past changes in global climate and carbon cycling as well as organismal evolution. However, this effort is still incomplete. Data remain sparse during the earlier part of the record and in some instances are dominated by estimates from a single proxy system. Generating a paleo-CO 2 record with even greater confidence will require further research using multiple proxies to fill in data gaps and increase overall data resolution, resolve discrepancies between estimates from contemporaneous proxy analyses, reduce uncertainty of established methods, and develop new proxies. Community-vetted quantitative CO 2 record. Paleo-CO 2 (including 95% credible intervals) is superimposed on the GMST trend over the past 66 million years. Age and CO 2 labels highlight notable climate extrema and transitions as described in the text.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2023
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    detail.hit.zdb_id: 2066996-3
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  • 2
    Online Resource
    Online Resource
    Proceedings of the National Academy of Sciences ; 2014
    In:  Proceedings of the National Academy of Sciences Vol. 111, No. 12 ( 2014-03-25)
    In: Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Vol. 111, No. 12 ( 2014-03-25)
    Type of Medium: Online Resource
    ISSN: 0027-8424 , 1091-6490
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    Language: English
    Publisher: Proceedings of the National Academy of Sciences
    Publication Date: 2014
    detail.hit.zdb_id: 209104-5
    detail.hit.zdb_id: 1461794-8
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  • 3
    In: Journal of Foraminiferal Research, Cushman Foundation for Foraminiferal Research, Vol. 50, No. 2 ( 2020-04-01), p. 128-140
    Abstract: Lake George (NY) is surrounded by Forever Wild Forest in the Adirondack Park and has a Class AA Special water quality rating, yet lake monitoring has revealed increasing anthropogenic impacts from salt and nutrient loading over the past 30 years. To reconstruct anthropogenic influence on the lake (e.g., salt loading, eutrophication, climate warming), we characterized modern stable isotopes and testate amoeba and diatom assemblages in surface sediments from 33 lake-wide sites and compared their variability to 36 years of water-quality data. Linear regression analyses support testate amoebae as rapid responders and recorders of environmental change because taxa are strongly correlated with percent change of important water quality parameters. Our assessment indicates that: 1) Netzelia gramen is associated with aquatic plants and filamentous algae, making them a valuable aquatic plant/alga indicator, which is supported by the co-occurrence of the diatom Cocconeis spp.; 2) difflugids are generally good indicators of eutrophication, except for Difflugia protaeiformis; and 3) seasonal differences in water quality trends are reflected in the fossil record on decadal time scales. We show that testate amoebae are highly sensitive to small environmental changes in an oligotrophic lake and exhibit established relationships from eutrophic and mesotrophic lakes as well as new, likely oligotrophic-specific correlations. Correlation coefficients of water quality variables and strains within a species also illustrate gradational relationships, suggesting testate amoebae exhibit ecophenotypic plasticity. Diatom and testate amoeba assemblages categorize modern lakebed sites into four subgroups: 1) benthic macrophyte; 2) high nutrient; 3) high alkalinity; and 4) salt loading assemblages.
    Type of Medium: Online Resource
    ISSN: 0096-1191
    Language: English
    Publisher: Cushman Foundation for Foraminiferal Research
    Publication Date: 2020
    detail.hit.zdb_id: 120390-3
    SSG: 12
    SSG: 13
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  • 4
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2017
    In:  Scientific Reports Vol. 7, No. 1 ( 2017-08-25)
    In: Scientific Reports, Springer Science and Business Media LLC, Vol. 7, No. 1 ( 2017-08-25)
    Abstract: The evolutionary success of reef-building corals is often attributed to photosymbiosis, a mutualistic relationship scleractinian corals developed with zooxanthellae; however, because zooxanthellae are not fossilized, it is difficult (and contentious) to determine whether ancient corals harbored symbionts. In this study, we analyze the δ 15 N of skeletal organic matrix in a suite of modern and fossil scleractinian corals (zooxanthellate- and azooxanthellate-like) with varying levels of diagenetic alteration. Significantly, we report the first analyses that distinguish shallow-water zooxanthellate and deep-water azooxanthellate fossil corals. Early Miocene (18–20 Ma) corals exhibit the same nitrogen isotopic ratio offset identified in modern corals. These results suggest that the coral organic matrix δ 15 N proxy can successfully be used to detect photosymbiosis in the fossil record. This proxy will significantly improve our ability to effectively define the evolutionary relationship between photosymbiosis and reef-building through space and time. For example, Late Triassic corals have symbiotic values, which tie photosymbiosis to major coral reef expansion. Furthermore, the early Miocene corals from Indonesia have low δ 15 N values relative to modern corals, implying that the west Pacific was a nutrient-depleted environment and that oligotrophy may have facilitated the diversification of the reef builders in the Coral Triangle.
    Type of Medium: Online Resource
    ISSN: 2045-2322
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2017
    detail.hit.zdb_id: 2615211-3
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  • 5
    Online Resource
    Online Resource
    Elsevier BV ; 2012
    In:  Earth and Planetary Science Letters Vol. 323-324 ( 2012-3), p. 27-39
    In: Earth and Planetary Science Letters, Elsevier BV, Vol. 323-324 ( 2012-3), p. 27-39
    Type of Medium: Online Resource
    ISSN: 0012-821X
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    Language: English
    Publisher: Elsevier BV
    Publication Date: 2012
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    SSG: 16,13
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  • 6
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2009
    In:  Journal of Geophysical Research: Atmospheres Vol. 114, No. D4 ( 2009-02-27)
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 114, No. D4 ( 2009-02-27)
    Abstract: The groundwater reservoir and its interaction with surface water facilitate lateral transport of continental water and energy. Current climate models do not account for long‐distance groundwater flow between model cells but route the atmospheric surplus (precipitation (P) minus evapotranspiration (ET)) directly to stream discharge within a model grid cell. We ask how much water exits a river basin without ever passing through its surface outlet? What are the climatologic and geologic factors influencing this flux? To answer these questions, a separation of groundwater flow from river flow is necessary. We use the ratio of stream discharge (Qr) to basin recharge (R = P − ET) for this purpose; where Qr:R 〈 1, a basin is considered a groundwater exporter; and where Qr:R 〉 1, a basin is considered a groundwater importer. Here Qr is obtained from 39 years of U.S. Geological Survey Hydro‐Climatic Data Network observed stream discharge from 1555 basins across the continental United States, and R (P − ET) is derived from 50 years of hydrologic simulation by the Variable Infiltration Capacity model. It was found that the Qr:R ratio deviates significantly from 1 across the continent. Detailed investigations of individual basins suggest that the deviations are primarily a function of geology, while climate and basin scale influence the magnitude of these deviations. Further, a marked incongruity between the surface and groundwater flow directions is apparent, suggesting that surface drainage is only partially indicative of subsurface flow regimes. The apparent significance of this long‐distance groundwater flow component reinforces the need for inclusion of the groundwater reservoir in current water cycle and climate modeling efforts.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2009
    detail.hit.zdb_id: 161666-3
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  • 7
    In: Energy & Fuels, American Chemical Society (ACS), Vol. 35, No. 22 ( 2021-11-18), p. 18135-18145
    Type of Medium: Online Resource
    ISSN: 0887-0624 , 1520-5029
    Language: English
    Publisher: American Chemical Society (ACS)
    Publication Date: 2021
    detail.hit.zdb_id: 56449-7
    detail.hit.zdb_id: 1483539-3
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  • 8
    Online Resource
    Online Resource
    American Association for the Advancement of Science (AAAS) ; 2011
    In:  Science Vol. 331, No. 6023 ( 2011-03-18), p. 1404-1409
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 331, No. 6023 ( 2011-03-18), p. 1404-1409
    Abstract: The effects of a large igneous province on the concentration of atmospheric carbon dioxide ( P co 2 ) are mostly unknown. In this study, we estimate P co 2 from stable isotopic values of pedogenic carbonates interbedded with volcanics of the Central Atlantic Magmatic Province (CAMP) in the Newark Basin, eastern North America. We find pre-CAMP P co 2 values of ~2000 parts per million (ppm), increasing to ~4400 ppm immediately after the first volcanic unit, followed by a steady decrease toward pre-eruptive levels over the subsequent 300 thousand years, a pattern that is repeated after the second and third flow units. We interpret each P co 2 increase as a direct response to magmatic activity (primary outgassing or contact metamorphism). The systematic decreases in P co 2 after each magmatic episode probably reflect consumption of atmospheric CO 2 by weathering of silicates, stimulated by fresh CAMP volcanics.
    Type of Medium: Online Resource
    ISSN: 0036-8075 , 1095-9203
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    Language: English
    Publisher: American Association for the Advancement of Science (AAAS)
    Publication Date: 2011
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    detail.hit.zdb_id: 2066996-3
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  • 9
    In: Limnology and Oceanography, Wiley, Vol. 63, No. 1 ( 2018-01), p. 107-121
    Abstract: Understanding the cellular and molecular responses of stony corals to ocean acidification is key to predicting their ability to calcify under projected high CO 2 conditions. Of specific interest are the links between biomineralization proteins and the precipitation of new calcium carbonate (CaCO 3 ), which potentially can provide a better understanding of the biomineralization process. We have assessed the effects of increased CO 2 on the calcification process in cell cultures of the stony coral, Stylophora pistillata , reared in nutrient‐enriched artificial seawater at four pCO 2 levels and two glucose concentrations. Dispersed S. pistillata cells grown at low (400 ppmV) and moderate (700 ppmV) pCO 2 re‐aggregate into proto‐polyps and precipitate CaCO 3 . When grown at pCO 2 levels of 1000 ppmV and 2000 ppmV, the cells up‐regulate genes for two highly acidic proteins as well as a carbonic anhydrase, but down‐regulate long term cadherin protein production and minimize proto‐polyp formation, and exhibit a significant decrease in measurable CaCO 3 precipitation. However, cell cultures precipitate CaCO 3 in all treatments, even at slightly undersaturated conditions (Ω aragonite   〈  0.95). Glucose addition does not influence either biomineralization gene expression or calcification rate. Measured δ 11 B of the mineral phase, as a proxy of the pH at the calcifying sites, is out of equilibrium with the ambient seawater medium surrounding the cells and proto‐polyps, suggesting pH is elevated in the micro‐environment of the precipitating mineral. Our results suggest that coral cells possess molecular mechanisms to help compensate for the effects of ocean acidification within the bounds projected in the coming century.
    Type of Medium: Online Resource
    ISSN: 0024-3590 , 1939-5590
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2018
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    detail.hit.zdb_id: 412737-7
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    SSG: 14
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  • 10
    Online Resource
    Online Resource
    The Royal Society ; 2018
    In:  Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences Vol. 376, No. 2130 ( 2018-10-13), p. 20170081-
    In: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, The Royal Society, Vol. 376, No. 2130 ( 2018-10-13), p. 20170081-
    Abstract: We have identified clear evidence of an extraterrestrial impact within the onset of the carbon isotope excursion (CIE) that defines the Palaeocene–Eocene (P-E) boundary hyperthermal event (approx. 56 Ma) from several sites on the eastern Atlantic Coastal Plain and offshore. We review and update the state of the evidence for an impact at the P-E boundary, including a K-Ar cooling age of the ejecta that is indistinguishable from the depositional age at the P-E, which establishes the ejecta horizon as an isochronous stratigraphic indicator at the P-E. Immediately above the ejecta peak at the base of the coastal plain Marlboro Clay unit, we identify a sharp increase in charcoal abundance coincident with the previously observed dramatic increase in magnetic nanoparticles of soil pyrogenic origin. We therefore revisit the observed sequence of events through the P-E boundary on the western Atlantic Coastal Plain, showing that an extraterrestrial impact led to wildfires, landscape denudation and deposition of the thick Marlboro Clay, whose base coincides with the spherule horizon and CIE onset. The Sr/Ca ratio of the spherules indicates that the carbon responsible for the onset may be vaporized CaCO 3 target rock mixed with isotopically light carbon from the impactor or elsewhere. Crucially, we do not argue that the impact was responsible for the full manifestation of the CIE observed globally (onset to recovery approx. 170 kyr), rather that a rapid onset was triggered by the impact and followed by additional carbon from other processes such as the eruption of the North Atlantic Igneous Province. Such a scenario agrees well with recent modelling work, though it should be revisited more explicitly. This article is part of a discussion meeting issue ‘Hyperthermals: rapid and extreme global warming in our geological past’.
    Type of Medium: Online Resource
    ISSN: 1364-503X , 1471-2962
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    Language: English
    Publisher: The Royal Society
    Publication Date: 2018
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    detail.hit.zdb_id: 1462626-3
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