In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 3 ( 2014-03-01), p. m92-m93
Abstract:
The title compound, [Pd(SC 6 H 4 F- p )Cl(PPh 3 ) 2 ]·0.5CH 3 OH, features a Pd II complex with two triphenylphosphane (PPh 3 ) ligands arranged in a trans conformation, with one chloride and one 4-fluorobenzenethiolate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd II ion. The methanol solvent molecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H...Cl hydrogen-bonding interactions between the complex molecules generate chain frameworks parallel to [010].
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814002499
DOI:
10.1107/S1600536814002499/hp2065sup1.cif
DOI:
10.1107/S1600536814002499/hp2065Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2041947-8
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