In:
Collection of Czechoslovak Chemical Communications, Institute of Organic Chemistry & Biochemistry, Vol. 64, No. 6 ( 1999), p. 947-958
Abstract:
[PtCl 2 (PMe 2 Ph) 2 ] and [(R'NH 2 )NB 8 H 11 NHR] (where both R' and R = Et or i-Pr and where R' = i-Pr, R = t -Bu) with NaH and air-exposure gives the series [3,3-(PMe 2 Ph) 2 -3-PtB 7 H 10 -μ-5,6-(NHR)] (33-44%) of which the structures are closely related to those of the open eight-boron hypho -type starting compounds [(R'NH 2 )B 8 H 11 NHR] by interchange of {BH(NH 2 R')} and {Pt(PMe 2 Ph)} vertices, with structural similarities to the rare arachno nine-vertex "normal" B 9 H 15 geometry. Related compounds from related reactions are [(PPh 3 ) 2 PtB 7 H 10 NHEt] and [(PMe 2 Ph) 2 PtB 7 H 10 NMe 2 ].
Type of Medium:
Online Resource
ISSN:
0010-0765
,
1212-6950
DOI:
10.1135/cccc19990947
Language:
English
Publisher:
Institute of Organic Chemistry & Biochemistry
Publication Date:
1999
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