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  • 1
    In: Aquatic Mammals, Aquatic Mammals Journal, Vol. 44, No. 3 ( 2018-05-15), p. 293-298
    Type of Medium: Online Resource
    ISSN: 0167-5427
    Language: Unknown
    Publisher: Aquatic Mammals Journal
    Publication Date: 2018
    detail.hit.zdb_id: 2129367-3
    SSG: 12
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  • 2
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2022
    In:  Journal of the Iranian Chemical Society Vol. 19, No. 10 ( 2022-10), p. 4017-4033
    In: Journal of the Iranian Chemical Society, Springer Science and Business Media LLC, Vol. 19, No. 10 ( 2022-10), p. 4017-4033
    Type of Medium: Online Resource
    ISSN: 1735-207X , 1735-2428
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 2244820-2
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  • 3
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2016
    In:  Sustainable Environment Research Vol. 26, No. 3 ( 2016-05), p. 136-141
    In: Sustainable Environment Research, Springer Science and Business Media LLC, Vol. 26, No. 3 ( 2016-05), p. 136-141
    Type of Medium: Online Resource
    ISSN: 2468-2039
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2016
    detail.hit.zdb_id: 2641138-6
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  • 4
    In: Sustainable Environment Research, Springer Science and Business Media LLC, Vol. 27, No. 1 ( 2017-01), p. 24-31
    Type of Medium: Online Resource
    ISSN: 2468-2039
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2017
    detail.hit.zdb_id: 2641138-6
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  • 5
    Online Resource
    Online Resource
    Sociedad Quimica de Mexico, A.C. ; 2018
    In:  Journal of the Mexican Chemical Society Vol. 62, No. 2 ( 2018-06-06)
    In: Journal of the Mexican Chemical Society, Sociedad Quimica de Mexico, A.C., Vol. 62, No. 2 ( 2018-06-06)
    Abstract: 〈 p 〉 The presence of mercury in soils, like other heavy metals, is associated with organic matter and minerals. Mercury deposited in soils is mainly in its oxidized form Hg2+. The adsorption of Hg (II) from aqueous solution into Ca-bentonite was studied. Adsorption percentage was determined as a function of shaking time and temperature to study the thermodynamics and kinetics of Hg (II) adsorption on Ca-bentonite, which was simulated using the MINSQ and GAUSSIAN 09 programs. 〈 /p 〉
    Type of Medium: Online Resource
    ISSN: 2594-0317 , 1870-249X
    Language: Unknown
    Publisher: Sociedad Quimica de Mexico, A.C.
    Publication Date: 2018
    detail.hit.zdb_id: 2210387-9
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  • 6
    In: Mexican Journal of Biotechnology, Mexican Journal of Biotechnology, Vol. 3, No. 2 ( 2018-04-01), p. 63-80
    Abstract: La crisis energética, la escasez del agua y la mala calidad del aire son temas que deben ser atendidos urgentemente con el objetivo de garantizar el bienestar de la población. El uso de tecnologías alternativas como los humedales construidos (HC) permiten el tratamiento de aguas residuales de diversa índole; cuando estas tecnologías son acopladas a sistemas bioelectroquímicos (SBE) se optimiza la remoción de la carga orgánica y se puede generar energía eléctrica. Así, el objetivo de este trabajo fue realizar un análisis de los avances, entre los años 2010 a 2017, sobre el diseño de diversas configuraciones de sistemas de HC acoplados a SBE. Se logró identificar las variables más importantes que determinan la eficiencia de remoción de contaminantes y generación de corriente como son los materiales anódico y catódico, el área de los electrodos, el tipo de macrófitas y la carga orgánica. Así mismo, se presentan los valores de la carga orgánica removida y las máximas densidades de potencia obtenidas con las tres macrófitas más utilizadas.
    Type of Medium: Online Resource
    ISSN: 2448-6590
    Uniform Title: Relevant aspects about design of constructed wetlands coupled to bioelectrochemical systems for wastewater treatment and energy generation
    URL: Issue
    Language: Spanish
    Publisher: Mexican Journal of Biotechnology
    Publication Date: 2018
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  • 7
    Online Resource
    Online Resource
    The Electrochemical Society ; 2018
    In:  ECS Meeting Abstracts Vol. MA2018-02, No. 27 ( 2018-07-23), p. 922-922
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2018-02, No. 27 ( 2018-07-23), p. 922-922
    Abstract: Helminths is a term designated to a wide group of organisms that includes all parasitic worms in fecal waste from animals and humans. They represent a high risk to human health because their various infectious stages (embryo, ova or larvae) are highly persistent in contaminated water, due to its large ability to survive for long periods, as they are extremely resistant to water disinfection treatments. Such resistance is given by the chemical composition of the layers of these eggs, mainly, formed by lipids and proteins. Thus, water constitutes a direct or indirect vehicle for the dissemination of helminths, even when they are found in low concentrations, giving rise to gastrointestinal diseases, especially when it is used to irrigate crops.There are some methods reported to remove Helminth ova, but the amin disadvantage is that these microorganisms are commonly inactivated but not destructed. There are other alternatives that promote disinfection through hydroxyl radical via Advanced Oxidation Processes (AOP).The objective of this study is to study the effect of an electro-Fenton treatment on water contaminated with helminth ova (HO). The inactivation of HO was studied in a continuous flow electro-Fenton reactor. Ion exchange resin was used to provide iron support, and H 2 O 2 was produced in situ by cathodic reduction of oxygen. In order to study the electro-Fenton efficiency, three treatments were run; treatment A: without electric current and without iron promoter, treatment B: applying a potential difference of -4V but without iron promoter; and treatment C: applying the aforementioned potential difference and with iron promoter. Treatment A represents the retention capacity of the system given by sorption capacity of involved materials, while B represents the electrochemical oxidation effect, and finally C represents the electro-Fenton effect. HO determination was carried out in the influent and effluent, as well as in the internal materials of the reactor; Fe (II)-ionic exchange resin, cathode (graphite cloth), activated carbon packed reactor, anode (graphite cloth) and Na-ionic exchange resin. It was possible to retain between 96.59% and 98.33% of HO admitted to the reactor, the higher inactivation was observed in treatment C (See Figure 1). The percentage of total HO, represents the amounts of HO both viable and non-viable. The percentage of viable HO was determined by trypan blue staining and incubation to verify HO viability. A low presence of viable HO could be observed in treatments B and C, while treatment C with electro-Fenton conditions produces hydroxyl radicals that have a high oxidizing potential which affects the layers of the HO. Control treatments A and B, compared to treatment C, presented higher percentages distribution for both total and viable HO, demonstrating that inactivation of HO is possible through the electro-Fenton process. The decrease in viable HO for treatments C with conditions suitable for electro-Fenton can serve as qualitative evidence that the Fenton reaction is taking place. Figure 1
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2018
    detail.hit.zdb_id: 2438749-6
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2018
    In:  ECS Meeting Abstracts Vol. MA2018-02, No. 27 ( 2018-07-23), p. 921-921
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2018-02, No. 27 ( 2018-07-23), p. 921-921
    Abstract: Biological methods are the most commonly used to treat effluents with high organic loads from sanitary water and industrial waste, mainly through aerobic fermentation. An effective alternative for water treatment are advanced oxidation methods, based on the Fenton reaction, where hydrogen peroxide (H 2 O 2 ) reacts with iron ions (Fe 2+ ) to obtain hydroxyl radicals (OH • ), with a power of oxidation of 2.8 V vs ENH. These methods have been used currently for the degradation of a wide range of pollutants, especially they have focused on the treatment of sanitary water in order to degrade pathogenic microorganisms. Therefore, the objective of this study was to evaluate the effect of the composition of a synthetic domestic wastewater, high in chlorides, which acts as an electrolyte in an electrochemical system named as electro-Fenton, where H 2 O 2 is obtained by oxygen reduction reaction. Water composition effect was studied in an electro-Fenton (EF) (1.4V) laboratory scale system consisting of a device packed with activated carbon (previously saturated with brilliant blue as model pollutant), with graphite cloth and iron mesh electrodes;in order to evaluate EF efficiency, the adsorption (A) and electro-oxidation (Eox) was compared in separate systems to treat a solution of direct blue 1 [20 mg / L] in 20 minutes. A control system composed of distilled water was used, where the aforementioned effects were also compared. The color concentration at the output of the reactor was evaluated by means of UV-Vis spectrophotometry, as well as the iron Fe 2+ and Fe TOT concentrations by phenanthroline method. Activated activated carbon was also analyzed by scanning electron microscopy (SEM) to determine whether each treatment promotes a change in the morphology into the activated carbon. As a result, it was obtained that the control system presented better discoloration results being: EF 〉 EOx 〉 A; unlike the system with synthetic residual water: A 〉 EF 〉 EOx with no significative difference between treatments. Distilled water showe 70% higher efficiency than synthetic water system. The pH and conductivity showed the same tendency as discoloration. The iron concentration at the system outlet was 5 mg/L of Fe 2+ and 6 mg/L of Fe TOT , for the control system; and 3 mg/L of Fe 2+ and 4 mg/L of Fe TOT in the synthetic wastewater system. It is concluded that the composition of synthetic water, mostly chlorides, favors the accumulation of chlorine ions in activated carbon, which interferes with the discoloration process, since the destruction of the dye molecule is limited. There is a decrease in pH and conductivity that is attributed to the Fenton reaction. SEM images showed differences between processes, as shown in the attached figure, which is attributed to the effect of formation of oxidizing species on the activated carbon surface. A greater difference is obscured in the Eox system, which suggests that the EF system is imitated by the high concentration of chlorine ions. Figure 1
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2018
    detail.hit.zdb_id: 2438749-6
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  • 9
    Online Resource
    Online Resource
    Walter de Gruyter GmbH ; 2017
    In:  International Journal of Chemical Reactor Engineering Vol. 15, No. 5 ( 2017-08-15)
    In: International Journal of Chemical Reactor Engineering, Walter de Gruyter GmbH, Vol. 15, No. 5 ( 2017-08-15)
    Abstract: Sorbent orange peel based materials activated using NaOH and H 3 PO 4 were prepared and evaluated in order to compare sorbent efficiency, and related to their physicochemical properties. Results of physicochemical characterization demonstrated there are significant changes on surface that promotes an adsorption behavior depending on the activation method. FTIR analysis shows decreasing signal of water at 3422 cm −1 of water, hemicellulose and pectin due to activation process, another decreasing signal is observed at at 1626 cm −1 for CC bond, while an increasing pick is observed at 1435 cm −1 which corresponds to methoxyl groups belonging to cellulosic compounds. Analysis of sorption equilibrium indicated 78 % of methyl orange sorption in orange dry peel (OP) which was sorbed after 5 hour, compared to 84 % and 98 % using 0.1 M activated sorbent material 2(AM2) and 0.6 M activated sorbent material 3 (AM3) H 3 PO 4 respectively, this process was carried out during the first 90 min of sorption process. NaOH activated sorbent material 1 (AM1) promoted 20 % to 65 % sorption. orange dry peel (OP), activated sorbent material 2 (AM2) and activated sorbent material 3 (AM3) obeyed a pseudo-second order kinetic model, while activated sorbent material 1 (AM1) obeys a pseudo-first order model. Sorption equilibrium of methyl orange resulted as follows, orange dry peel (OP) followed a Freundlich equilibrium model, activated sorbent material 1 (AM1) a Langmuir model, while activated sorbent material 2 (AM2) and activated sorbent material 3 (AM3) to Hill model. Activated sorbent materials with H 3 PO 4 showed 750–770 mg/g of methyl orange which represent high sorption capacities. Orange peel sorbent material previously activated with H 3 PO 4 represents a good alternative to reduce water pollution, and also residues of orange peel could be reduced by this alternative treatment.
    Type of Medium: Online Resource
    ISSN: 1542-6580
    Language: Unknown
    Publisher: Walter de Gruyter GmbH
    Publication Date: 2017
    detail.hit.zdb_id: 2112754-2
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  • 10
    In: Molecules, MDPI AG, Vol. 26, No. 15 ( 2021-07-28), p. 4555-
    Abstract: Chemical and thermochemical transformations were performed on orange peel to obtain materials that were characterized and further tested to explore their potential as adsorbents for the removal of methylene blue (MB) from aqueous solutions. The results show the high potential of some of these materials for MB adsorption not only due to the surface area of the resulting substrate but also to the chemistry of the corresponding surface functional groups. Fitting of the kinetic as well as the equilibrium experimental data to different models suggests that a variety of interactions are involved in MB adsorption. The overall capacities for these substrates (larger than 192.31 mg g−1) were found to compare well with those reported for activated carbon and other adsorbents of agro-industrial origin. According to these results and complementary with theoretical study using Density Functional Theory (DFT) approximations, it was found that the most important adsorption mechanisms of MB correspond to: (i) electrostatic interactions, (ii) H-bonding, and (iii) π (MB)–π (biochar) interactions. In view of these findings, it can be concluded that adsorbent materials obtained from orange peel, constitute a good alternative for the removal of MB dye from aqueous solutions.
    Type of Medium: Online Resource
    ISSN: 1420-3049
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2008644-1
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