In:
Green Processing and Synthesis, Walter de Gruyter GmbH, Vol. 5, No. 1 ( 2016-1-1), p. 71-77
Abstract:
A simple and environmentally benign procedure for the bromination of substituted α,β-unsaturated ketones in good yield has been described using ammonium bromide as a brominating agent and ceric ammonium nitrate (CAN) as a single-electron oxidant to afford α,β-dibromoketones. The reaction involves C-Br bond formation by radical method generated by CAN. The reaction can be carried out by either at room temperature, stirring in solvent CH 3 CN or under aqueous moist condition with few drops of water by manual grinding in a mortar and pestle.
Type of Medium:
Online Resource
ISSN:
2191-9550
,
2191-9542
DOI:
10.1515/gps-2015-0097
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2016
detail.hit.zdb_id:
2645923-1
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