In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 72, No. 11 ( 2017-11-27), p. 839-846
Abstract:
The compounds [W(CO) 5 (btd)], [W(CO) 5 (bsd] and [Re(CO) 3 (bpy)(bsd)](BF 4 ), btd=2,1,3-benzothiadiazole and bsd=2,1,3-benzoselenadiazole were isolated and characterized experimentally (crystal structure, spectroscopy, spectroelectrochemistry) and by density functional theory calculations. The results confirm single N-coordination in all cases, binding to Se was calculated to be less favorable. Studies of one-electron reduced forms indicate that the N-coordination is maintained during electron transfer.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2017-0100
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2017
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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