In:
Molecular Systems Design & Engineering, Royal Society of Chemistry (RSC), Vol. 7, No. 7 ( 2022), p. 788-797
Abstract:
Sequential vapor doping is a vital process in controlling the electronic transport properties of semiconducting polymers relevant to opto-electronic and thermoelectric applications. Here, we employed an in situ conductivity method to determine the temporal electronic conductivity ( σ ) profile when vapor 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) doping poly(3-hexylthiophene) (P3HT) thin films held at a different temperatures. The temporal profile of σ first showed a fast exponential increase, followed by a brief linear increase until reaching a σ max , and followed by a slow decay in σ . The σ profile were correlated to structural changes through a combination UV-vis-NIR spectroscopy, X-ray scattering, and Raman spectroscopy. We find that the timing for σ max , and subsequent drop in σ of P3HT:F4TCNQ thin films corresponds to the evolution of doping in the crystalline (ordered) and amorphous (disordered) domains. Specifically, Raman spectroscopy resonant at 785 nm highlighted that the crystalline domains reached their saturated doping level near σ max and subsequent smaller level of doping occurred in regions in the disordered domains. Overall, this study emphasizes the importance of granular understanding of σ and the corresponding structural changes in the crystalline and amorphous domains.
Type of Medium:
Online Resource
ISSN:
2058-9689
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
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