In:
Journal of Materials Research, Springer Science and Business Media LLC, Vol. 24, No. 9 ( 2009-09), p. 2762-2766
Abstract:
The effects of ruthenium (Ru)-oxidation states were investigated on Ru dissolution from PtRu thin-film electrodes, with the 200 cycles between 0.4 and 1.05 V (versus normal hydrogen electrode). The Ru-oxidation states of the PtRu thin films were systematically modified by an anodic (oxidation) treatment. The anodic-treated PtRu electrodes, whose methanol-oxidation activity was similar to untreated electrodes before the 200 cycles, showed a remarkable decrease in methanol oxidation after the cycles, because of the Ru dissolution from the PtRu surface. The results suggest that the Ru-oxide species are the origin of Ru dissolution in the PtRu alloy.
Type of Medium:
Online Resource
ISSN:
0884-2914
,
2044-5326
DOI:
10.1557/jmr.2009.0331
Language:
English
Publisher:
Springer Science and Business Media LLC
Publication Date:
2009
detail.hit.zdb_id:
54876-5
detail.hit.zdb_id:
2015297-8
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