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  • 1
    In: BioScience, Oxford University Press (OUP), Vol. 62, No. 6 ( 2012-6), p. 562-574
    Type of Medium: Online Resource
    ISSN: 1525-3244 , 0006-3568
    RVK:
    Language: English
    Publisher: Oxford University Press (OUP)
    Publication Date: 2012
    detail.hit.zdb_id: 2066019-4
    SSG: 12
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  • 2
    Online Resource
    Online Resource
    International Oil Spill Conference ; 1993
    In:  International Oil Spill Conference Proceedings Vol. 1993, No. 1 ( 1993-03-01), p. 407-413
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1993, No. 1 ( 1993-03-01), p. 407-413
    Abstract: Depositional oil and soot derived from the 1991 Kuwait oil field fires produced huge tar mats in the desert. The concentration of oil in the upper 5 cm of the desert surface ranged from 1.16 to 8.92 percent oil by weight as determined by TPH analysis over a 10 km transect in southern Kuwait. The mean concentration of asphaltenes in the tar mat samples was estimated at 62 percent; a greater than 17-fold increase in concentration over unweathered Kuwait crude oil. The remaining oil forming these tar mats is believed to be derived from petroleum that escaped combustion within the well fires. Results from GC/MS analyses characterize the depositional oil as being significantly altered by evaporative weathering. We suspect that evaporation of the depositional oil will continue, further consolidating the weathered oil, sand, and soot into asphalt-like zones which will remain for a very long time as features of the Kuwait desert. Significant quantities of oil residue from the fires also fell into the Arabian Gulf, contributing to what may be the largest man-made oil spill.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1993
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  • 3
    Online Resource
    Online Resource
    International Oil Spill Conference ; 1993
    In:  International Oil Spill Conference Proceedings Vol. 1993, No. 1 ( 1993-03-01), p. 891A-891
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1993, No. 1 ( 1993-03-01), p. 891A-891
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1993
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  • 4
    Online Resource
    Online Resource
    International Oil Spill Conference ; 1997
    In:  International Oil Spill Conference Proceedings Vol. 1997, No. 1 ( 1997-04-01), p. 936-937
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1997, No. 1 ( 1997-04-01), p. 936-937
    Abstract: Forensic approaches for differentiating spilled oils, tar balls, and oil-contaminated sediments by source can be enhanced by converting qualitative GC/MS data to quantitative values and applying statistical data analyses. Such techniques reduce the potential for chemist bias and fatigue that can result in false-positive and false-negative determinations. The suite of indexes used by our laboratory are highly discriminating, resistant to oil weathering and biodegradation, and are not subject to most day-to-day laboratory variances. We have applied the term “self-normalizing fingerprint indexes” (SFIs) to label such parameters or ratios. The SFI approach has been demonstrated to reduce investigator bias and highlight subtle differences in actual spill samples and baseline monitoring studies that might have been missed by standard qualitative approaches to source-fingerprinting. This approach represents another step in the development of legally defensible methods of oil spill response.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1997
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  • 5
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 2014, No. 1 ( 2014-05-01), p. 604-617
    Abstract: The Coastal Waters Consortium (CWC) led by Louisiana Universities Marine Consortium is one of eight Gulf of Mexico Research Initiative research consortia. The CWC focuses on: oil transport and fate, chemical evolution and biological degradation, and environmental effects.The following is an overview of a portion of the research conducted within the consortium. The consortium works in a system that was impacted by the Deepwater Horizon oil disaster and additionally impacted by freshwater diversions resulting in changes in salinity, tropical storms, and hurricanes. First, we conducted model simulations assessing oil transport into the Barataria Bay estuary, which indicate that easterly winds and feeding of the anticyclonic gyre in the Louisiana Bight pushed the oil into Barataria Bay. In subtidal sediments adjacent to oiled marshes, marsh detritus from eroding marsh edges eventually became entrained in the sediment column. Biotic impacts vary. The above-ground plant biomass appears healthy at the individual sampling sites; overall the most seaward (i.e., likely oil-impacted) areas of Terrebonne and Barataria Bay have shown, via satellite data, a distinct decline in marsh vegetation coverage since 2010. Oysters appear to be affected by predation and salinity variation. Microbial diversity from marsh-edge sediments is distinct from before and after the spill, and between unoiled and oiled marshes, with lower diversity in oiled marshes; but the greatest community composition shifts are in marshes affected by the freshwater diversions. Changes in microbial diversity in the water column at the stream-side edge of oiled marshes are extensive and are related to marsh edge erosion. In contrast, oiling of marshes had no impact on ammonia oxidizer or denitrifier abundances and on soil biogeochemical process rates 2+ years post-spill. Analysis of long-term offshore phytoplankton community and hypoxia data indicate some signal of the Macondo oil, but these components of the ecosystem remain mostly influenced by the fresh water and nutrients delivered by the Mississippi River. The consortium continues to work to tease apart oil impacts, effects of salinity, natural variation, and disturbance from tropical storms and hurricanes to determine the trajectory for health of shelf waters and Louisiana's marshes.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 2014
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  • 6
    Online Resource
    Online Resource
    International Oil Spill Conference ; 1999
    In:  International Oil Spill Conference Proceedings Vol. 1999, No. 1 ( 1999-03-01), p. 225-228
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1999, No. 1 ( 1999-03-01), p. 225-228
    Abstract: A flow-through fluorometry system is a valuable tool for measuring dispersed oil concentrations real-time in freshwater and marine environments. As part of the new Scientific Monitoring of Advanced Response Technologies (SMART), fluorometers are used to investigate dispersant efficacy and dispersed oil transport. Using fluorometers in situ to accurately measure dispersed oil concentrations is not a trivial task: detector response values vary due to oil composition, oil weathering changes response factors, dispersed oil is not a true solution, and natural waters contribute matrix effects and background fluorescence. Based on recent experiences and building upon research conducted in the 1980's, the most effective and accurate method to estimate the dispersed oil concentrations is through real-time water grab samples analyzed by laboratory methodologies for in vitro dispersed oil toxicity quantification. Once analyzed, the field water results can be used to establish a response curve, converting raw field response values into oil concentrations. The continuous record created by the flow-through fluorometer provides a far more comprehensive assessment than collecting a few water samples for laboratory analysis. The combination of using a real-time fluorometer in conjunction with field water sampling is a far superior approach than either method alone. The art and science of in situ fluorometry for measuring dispersed oil will be demonstrated using both laboratory and actual field data.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1999
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  • 7
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1995, No. 1 ( 1995-02-01), p. 97-100
    Abstract: Although bioremediation for oil spill cleanup has received considerable attention in recent years, its satisfactory use in the cleanup of oil spills in the wetland environment is still questionable and generally untested. We have initiated a multidisciplinary experimental program to evaluate the use of both microbial seeding and fertilizer as means of enhancing oil biodegradation in coastal salt marshes. We are utilizing controlled greenhouse experiments as well as field trials to test the efficacy and ecological safety of these enhanced biodegradation methodologies. This paper summarizes the overall scope of the study and presents some preliminary findings concerning marsh plant response to the bioremediation agents. We shall report on the results of the first year of this three-year investigation. Sods of marsh (soil and vegetation intact), approximately 30 cm in diameter and 25 cm deep, collected from the inland zone of a Spartina alterniflora dominated salt marsh in south Louisiana were used in a greenhouse experiment to identify the effects on plant and soil responses of the following treatments, with and without oil: seeding product, fertilizer product, and control (no product). Mesocosms were sampled for petroleum hydrocarbon chemistry to identify and quantify the degree of oil biodegradation, soil microbial response to determine the effect of the bioremediation products on the microbial communities that are performing the oil biodegradation, soil chemistry to determine the effect of the bioremediation products (such as nutrients, soil reducing conditions, and soil toxins) on those factors that limit the growth of microbes and plants, and plant response to evaluate the effects of the oil and products on plant vigor and growth. This paper presents selected plant responses that demonstrated that the bioremediation products tested had no adverse impact on plant growth. Additionally, soil respiration was increased by fertilizer, but not microbial, application.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1995
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  • 8
    Online Resource
    Online Resource
    International Oil Spill Conference ; 1995
    In:  International Oil Spill Conference Proceedings Vol. 1995, No. 1 ( 1995-02-01), p. 185-189
    In: International Oil Spill Conference Proceedings, International Oil Spill Conference, Vol. 1995, No. 1 ( 1995-02-01), p. 185-189
    Abstract: Source identification of spilled petroleum during incidents is a crucial piece of information required for response activities. The need for rapid, accurate assessment is essential at the onset of a spill to determine the extent and impacts of the incident. This necessity for speed becomes less important as cleanup progresses. Current fingerprinting methods utilize gas chromatography/mass spectroscopy (GC/MS) and have become an important analytical tool because of high selectivity and compound specificity. Disadvantages include time requirements for sample preparation and analysis in addition to the use of soon-to-be-banned chlorinated solvents. Sample analyses may require up to eight hours a sample when using standard techniques. We are currently developing methods to reduce the turnaround time by alternate sample preparation and rapid analysis; primarily through use of thermal extraction and short, narrow-bore capillary columns. This technique can greatly reduce analysis time without sacrificing important chromatographic information. Samples from recent oil spills were compared by standard GC/MS fingerprinting to the fast chromatographic method developed in our laboratory. The identification clarity capability of the faster method is shown by the inclusion of various characteristic biomarkers—such as the more resistant, yet toxic, polycyclic aromatic hydrocarbons, geological biomarker triterpanes and steranes, as well as compounds indicative of weathering and degradation stages.
    Type of Medium: Online Resource
    ISSN: 2169-3358 , 2169-3366
    Language: English
    Publisher: International Oil Spill Conference
    Publication Date: 1995
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  • 9
    Online Resource
    Online Resource
    Informa UK Limited ; 2008
    In:  Environmental Forensics Vol. 9, No. 1 ( 2008-03-17), p. 63-74
    In: Environmental Forensics, Informa UK Limited, Vol. 9, No. 1 ( 2008-03-17), p. 63-74
    Type of Medium: Online Resource
    ISSN: 1527-5922 , 1527-5930
    Language: English
    Publisher: Informa UK Limited
    Publication Date: 2008
    detail.hit.zdb_id: 2018852-3
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  • 10
    In: Microchemical Journal, Elsevier BV, Vol. 174 ( 2022-03), p. 107074-
    Type of Medium: Online Resource
    ISSN: 0026-265X
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2022
    detail.hit.zdb_id: 1471165-5
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