In:
Plasma Processes and Polymers, Wiley, Vol. 20, No. 10 ( 2023-10)
Abstract:
A surface dielectric barrier discharge reactor was applied in the removal of oxygen traces from coke oven gas (COG), to which toluene was added as a model hydrocarbon contaminant. The adverse effect of toluene on O 2 conversion was observed in a H 2 /N 2 /O 2 mixture, while in synthetic COG consisting of H 2 , CH 4 , N 2 , CO, CO 2 , and O 2 , it remained unchanged. Online gas chromatography (GC) showed that the reactivity of toluene is mainly driven by H 2 /N 2 /O 2 . The accumulated residue was dissolved and analyzed by GC coupled with mass spectrometry. The identified reaction products suggest that toluene undergoes ring‐opening and functionalization.
Type of Medium:
Online Resource
ISSN:
1612-8850
,
1612-8869
DOI:
10.1002/ppap.202300084
Language:
English
Publisher:
Wiley
Publication Date:
2023
detail.hit.zdb_id:
2159694-3
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