In:
ECS Journal of Solid State Science and Technology, The Electrochemical Society, Vol. 11, No. 5 ( 2022-05-01), p. 055005-
Abstract:
In this perspective, we discuss complex charge transport behaviours induced by redox-reactions in molecular tunnelling junctions by gauging the development of charge transport theories which allow for more unified approaches between temperature-dependent and -independent transport. A context is drawn for current experimental works which previously demonstrated behaviours that could not have been explained by traditional Marcus and Landauer theories. The work discusses not only the reported temperature-independent long-range tunnelling and their corresponding theoretical explanations but also correlates the influence of structural and thermodynamic factors that influence such peculiar temperature dependencies in molecular junctions.
Type of Medium:
Online Resource
ISSN:
2162-8769
,
2162-8777
DOI:
10.1149/2162-8777/ac6d0d
Language:
Unknown
Publisher:
The Electrochemical Society
Publication Date:
2022
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