In:
Collection of Czechoslovak Chemical Communications, Institute of Organic Chemistry & Biochemistry, Vol. 62, No. 7 ( 1997), p. 1089-1094
Abstract:
The first stereoselective synthesis of 2α,3α-epoxy-9β-benzoyloxy-β-agarofuran ( 3 ) and 2,3-dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran ( 4 ) from (-)-carvone in 13 steps, respectively, has been described. In addition, the synthesis of 2,3-dehydro-4β,9β-dihydroxy-β-dihydroagarofuran ( 13 ) has also been reported. By the reduction of 4 to give 13 , the 4β,12-epoxy configuration of 4 was established.
Type of Medium:
Online Resource
ISSN:
0010-0765
,
1212-6950
DOI:
10.1135/cccc19971089
Language:
English
Publisher:
Institute of Organic Chemistry & Biochemistry
Publication Date:
1997
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