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  • 1
    Online Resource
    Online Resource
    AIP Publishing ; 2004
    In:  Journal of Applied Physics Vol. 96, No. 11 ( 2004-12-01), p. 6113-6119
    In: Journal of Applied Physics, AIP Publishing, Vol. 96, No. 11 ( 2004-12-01), p. 6113-6119
    Abstract: One and three bilayers of HfO2(9Å)∕Al2O3(3Å) thin films were grown by atomic layer chemical-vapor deposition on Si(001) substrates whose surfaces were nitrided or oxidized. The films as-grown and postannealed in an ultrahigh vacuum were analyzed by atomic force microscopy, photoelectron spectroscopy, and medium energy ion scattering. For the one- and three-bilayer films grown on the nitrided Si substrates, the HfO2 and Al2O3 layers are mixed to form Hf aluminates at temperatures above 600°C. The mixed Hf aluminate layer is partly decomposed into HfO2 and Al2O3 grains and Al2O3 segregates to the surface by postannealing at 900°C. Complete decomposition takes place at 1000°C and the surface is covered with Al2O3. The surfaces are uniform and almost flat up to 900°C but are considerably roughened at 1000°C due to the complete decomposition of the Hf aluminate layer. In contrast, for one- bilayer films stacked on the oxidized Si substrates, Hf silicate layers, including Hf aluminate, are formed by annealing at 600–800°C. At temperatures above 900°C, HfSi2 grows and Al oxide escapes from the surface.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2004
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 2
    Online Resource
    Online Resource
    Elsevier BV ; 1991
    In:  Physica C: Superconductivity Vol. 190, No. 1-2 ( 1991-12), p. 114-115
    In: Physica C: Superconductivity, Elsevier BV, Vol. 190, No. 1-2 ( 1991-12), p. 114-115
    Type of Medium: Online Resource
    ISSN: 0921-4534
    Language: English
    Publisher: Elsevier BV
    Publication Date: 1991
    detail.hit.zdb_id: 392532-8
    detail.hit.zdb_id: 1467152-9
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  • 3
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-01, No. 36 ( 2014-04-01), p. 1373-1373
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-01, No. 36 ( 2014-04-01), p. 1373-1373
    Abstract: Y. X. Liu, T. Matsukawa, K. Endo, S. O’uchi, J. Tsukada, H. Yamauchi, Y. Ishikawa, W. Mizubayashi, Y. Morita, S. Migita, H. Ota, and M. Masahara National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 2, 1-1-1 Umezono, Tsukuba-shi, Ibaraki 305-8568, Japan. Tel: +81-29-861-3417, Fax: +81-29-861-5170, E-mail: yx-liu@aist.go.jp Three-dimensional (3D) fin-channel devices provide excellent short-channel effect (SCE) immunity thanks to the strong controllability of channel potential by the multiple gates. Therefore, the scaled charge trapping (CT) type FinFET flash memories have actively been developed in the past few years (1-3). Very recently, we have also developed floating gate (FG) type SOI-FinFET flash memories with different gate structures (4, 5), and experimentally confirmed that tri-gate (TG) structure shows the better SCE immunity and a larger memory window than double-gate (DG) structure. As a further study, in this work, we fabricate CT type TG-structured SOI-FinFET flash memories with different gate materials and different blocking layer materials, and comparatively investigate their electrical characteristics. 1. Device Fabrication In the device fabrication, we used (110)-oriented SOI wafers, and the Si-fin channels were fabricated by using orientation dependent wet etching (6). To fabricate TG structure, the SiO 2 fin hard-mask layer was removed by RIE. Then, a 4.3-nm-thick tunnel oxide was formed by thermal oxidation, followed by the deposition of a 10-nm-thick nitride (Si 3 N 4 ) layer by LPCVD. As the blocking layer, a 10-nm-thick Al 2 O 3 layer or a 9-nm-thick SiO 2 layer was deposited on the different sample wafers. As the different gate materials, we used n + -poly-Si and PVD-TiN metal. Figure 1(a) shows the SEM image of the fabricated FinFET flash memory with a scaled gate length (L g ) of 26 nm. The cross-sectional STEM images of the fabricated n + -poly-Si gate SONOS, PVD-TiN metal gate MONOS and MANOS with a high-k Al 2 O 3 blocking layer are shown in Figs. 1(b), 1(c) and 1(d), respectively. It is clear that uniform and ultrathin Si-fin channels are successfully fabricated thanks to the orientation dependent wet etching. 2. Gate Material Dependent of Memory Property At first, we measured the initial I d -V g characteristics of the fabricated SONOS and MONOS type FinFET flash memories, and the threshold voltage (V t ) values were evaluated at a constant drain current of I d = 1 mA. It was experimentally found that almost the same sV t is obtained in the SONOS and MONOS devices. This result indicates that V t variation is independent of gate material. Then, we measured P/E characteristics of the fabricated SONOS and MONOS devices. It was found that a larger memory window is obtained in the MONOS devices than the SONOS ones due to the higher work function of PVD-TiN gate than the n + -poly-Si gate as shown in Fig. 2. The higher gate work function is effective to the suppression of electron back tunneling during erase operation [7]. 3. Blocking Layer Dependent of Memory Property To investigate blocking layer material dependence on the electrical characteristics of the CT type FinFET flash memories, we fabricated MONOS and MANOS type devices with different blocking layers of SiO 2 and Al 2 O 3 as mentioned before. The initial I d -V g characteristics of the fabricated MONOS and MANOS type FinFET flash memories with different L g values from 26 to 103 nm were measured and the SCE immunity was systematically evaluated. It was found that the smaller V t roll-off and the better subthreshold slope (S-slope) are observed in the MANOS devices as compared to the MONOS ones due to the high-k effect of Al 2 O 3 in MANOS devices. The P/E characteristics of the fabricated MONOS and MANOS devices were also comparatively investigated. It was found that a significant memory window increment is obtained by introducing an Al 2 O 3 blocking layer instead of the SiO 2 one as shown in Fig. 3. This result is reasonable because a high-k Al 2 O 3 blocking layer is effective to enhance the electric field across the tunnel oxide layer and to reduce the electric field across itself. Therefore, electron back tunneling from the gate to nitride layer is effectively suppressed during erase operation. As a result, a deep erase and a large memory window are obtained in the MANOS devices than the MONOS ones. It was also confirmed that the fabricated MONOS and MANOS devices can operate over 100 k cycles, and can maintain a reasonable memory window after 10 years. In summary, we have investigated the gate material and blocking layer material dependences on the electrical characteristics of the fabricated CT type FinFET flash memories. It was experimentally found that a high work function metal gate and a high-k blocking layer are very useful to the enhancement of memory window. Acknowledgment: This work was supported in part by the Nanotechnology Project of NEDO, Japan. [1] P. Xuan et al., IEDM Tech. Dig., 609 (2003). [2] M. Spechi et al., IEDM Tech. Dig., 1083 (2004). [3] S-K. Sung et al., Symp. VLSI Tech. Dig., 106 (2006). [4] Y. X. Liu et al., Ext. Abstract, SSDM, 985 (2011). [5] T. Kamei et al., IEEE EDL 33 345 (2012). [6] Y. X. Liu et al., IEEE EDL 24 484 (2003). [7] C. H. Lee et al., IEDM Tech. Dig., 613 (2003).
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
    detail.hit.zdb_id: 2438749-6
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2003
    In:  Applied Physics Letters Vol. 83, No. 21 ( 2003-11-24), p. 4306-4308
    In: Applied Physics Letters, AIP Publishing, Vol. 83, No. 21 ( 2003-11-24), p. 4306-4308
    Abstract: The coordination and interface of Al2O3 formed on Si(001) by atomic layer deposition (ALD) were studied using electron energy-loss spectroscopy in a transmission electron microscope. Al energy-loss near-edge structures (ELNESs) were interpreted using first-principles calculations. The Al L23 ELNESs show two peaks at 78.2 and 79.7 eV, which originate from tetrahedrally and octahedrally coordinated aluminum, respectively. The depth profile of coordination in ALD Al2O3/Si was investigated. While both tetrahedrally and octahedrally coordinated Al atoms exist in the ALD Al2O3, the former is dominant near the interface. Aluminum silicate was detected near the interface, and it may cause the difference in aluminum coordination.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2003
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 5
    In: Journal of Applied Physics, AIP Publishing, Vol. 114, No. 16 ( 2013-10-28)
    Abstract: FePt thin films with a thickness of 30 nm were deposited by dc magnetron sputtering at room temperature onto SiO2(100 nm)/Si(100) substrates. These films were post-annealed in a temperature range of 500 °C to 900 °C for 30 s in three different atmospheres—N2, Ar, and forming gas (Ar+H2 (3 vol. %)). Irrespective of the annealing atmosphere, the chemically ordered L10 FePt phase has formed after annealing at 500 °C. Higher annealing temperatures in N2 or Ar atmosphere resulted in a strong increase in grain size and surface roughness but also in the appearance of a pronounced (001) texture in the FePt films. However, these films show the presence of iron oxide. In contrast, annealing in forming gas atmosphere suppressed the oxidation process and resulted in a reduced grain size and lower surface roughness. However, no (001)—but a strong (111)—texture was obtained after annealing at 700 °C, which might be related to the reduced unit cell tetragonality and incorporation of hydrogen to the FePt lattice. Thus, this study clearly demonstrates that the oxygen/hydrogen content plays an important role in controlling the crystallographic orientation during post-annealing.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2013
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 6
    Online Resource
    Online Resource
    IOP Publishing ; 1991
    In:  Superconductor Science and Technology Vol. 4, No. 9 ( 1991-09-01), p. 488-490
    In: Superconductor Science and Technology, IOP Publishing, Vol. 4, No. 9 ( 1991-09-01), p. 488-490
    Type of Medium: Online Resource
    ISSN: 0953-2048 , 1361-6668
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 1991
    detail.hit.zdb_id: 1361475-7
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  • 7
    In: Journal of Applied Physics, AIP Publishing, Vol. 116, No. 4 ( 2014-07-28)
    Abstract: Pt/Fe and Pt/Ag/Fe layered films were deposited by DC magnetron sputtering on MgO(001), SrTiO3(001), and Al2O3(0001) single crystalline substrates at room temperature. The films were post-annealed between 623 K and 1173 K for 30 s in flowing N2 atmosphere. The onset of the L10-FePt phase formation in films deposited on MgO(001) and SrTiO3(001) substrates was observed after annealing between 773 and 873 K, while chemical L10 ordering sets in for Pt/Fe bilayers on Al2O3(0001) at lower temperatures accompanied by strong (001)-texture. It is concluded that elastic stress, arising from the difference in thermal expansion coefficients between film and substrate, promotes ordering and texture formation.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2014
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Transactions Vol. 61, No. 2 ( 2014-03-24), p. 263-280
    In: ECS Transactions, The Electrochemical Society, Vol. 61, No. 2 ( 2014-03-24), p. 263-280
    Abstract: The charge trapping (CT) type tri-gate (TG) silicon on insulator (SOI) FinFET flash memories with different gate and blocking layer materials have successfully been fabricated, and their electrical characteristics including short-channel effect (SCE) immunity, threshold voltage (V t ) variability and memory property have comparatively been investigated. It was experimentally found that a large memory window is obtained in the physical vapor deposited (PVD) titanium nitride (TiN) metal gate flash memories than the n + -poly-Si gate ones owing to the higher work function of PVD-TiN metal gate, which is effective to suppress electron back tunneling during erase operation. It was also confirmed that the better SCE immunity and a significant improvement in memory window are observed by introducing a high-k Al 2 O 3 blocking layer into the PVD-TiN metal gate flash memories. Moreover, it was found that the V t variations before and after a program/erase (P/E) cycle are independent of the gate and blocking layer materials.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 9
    In: Nanoindustry Russia, Technosphera JSC, , No. 1 ( 2016), p. 94-109
    Type of Medium: Online Resource
    ISSN: 1993-8578
    Uniform Title: На пути к нейроморфной мемристорной компьютерной платформе
    URL: Issue
    Language: Unknown
    Publisher: Technosphera JSC
    Publication Date: 2016
    detail.hit.zdb_id: 3021337-X
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  • 10
    Online Resource
    Online Resource
    Elsevier BV ; 2006
    In:  Materials Science in Semiconductor Processing Vol. 9, No. 6 ( 2006-12), p. 975-979
    In: Materials Science in Semiconductor Processing, Elsevier BV, Vol. 9, No. 6 ( 2006-12), p. 975-979
    Type of Medium: Online Resource
    ISSN: 1369-8001
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2006
    detail.hit.zdb_id: 2029689-7
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