In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 51, No. 5 ( 2022), p. 1901-1906
Kurzfassung:
The coordination behaviour of multinuclear clusters to fused arene ligands is of continuous interest due to its relevance to metal catalysts supported by graphitic carbon materials. Herein, we report the bridging coordination behaviour of acenaphthylene to a Pd 3 or a Pd 4 cluster. A bis-acenaphthylene Pd 3 chain cluster and an acenaphthylene-COT Pd 4 sheet cluster were isolated, and the μ 3 -π-coordination mode or the μ 4 -oxidative π-addition mode of the acenaphthylene ligand in each cluster was elucidated by X-ray structure analysis.
Materialart:
Online-Ressource
ISSN:
1477-9226
,
1477-9234
Sprache:
Englisch
Verlag:
Royal Society of Chemistry (RSC)
Publikationsdatum:
2022
ZDB Id:
1472887-4
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