In:
Angewandte Chemie, Wiley, Vol. 132, No. 44 ( 2020-10-26), p. 19636-19645
Abstract:
A series of structurally diverse alcoholamine‐ and alkoxyalkylamine‐functionalized variants of the metal–organic framework Mg 2 (dobpdc) are shown to adsorb CO 2 selectively via cooperative chain‐forming mechanisms. Solid‐state NMR spectra and optimized structures obtained from van der Waals‐corrected density functional theory calculations indicate that the adsorption profiles can be attributed to the formation of carbamic acid or ammonium carbamate chains that are stabilized by hydrogen bonding interactions within the framework pores. These findings significantly expand the scope of chemical functionalities that can be utilized to design cooperative CO 2 adsorbents, providing further means of optimizing these powerful materials for energy‐efficient CO 2 separations.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v132.44
DOI:
10.1002/ange.201915561
Language:
English
Publisher:
Wiley
Publication Date:
2020
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