In:
Applied Physics Letters, AIP Publishing, Vol. 100, No. 18 ( 2012-04-30)
Abstract:
Aberration corrected scanning transmission electron microscopy revealed that Bi0.85Nd0.15Fe0.9Ti0.1O3 ceramics contain coherent Nd-rich precipitates distributed throughout the perovskite lattice, implying charge compensation is obtained by the creation of VNd/// and not VBi///. At low concentrations, therefore, Ti4+ replace Fe2+ with the creation of 2/3VNd///, and at higher concentrations (when Fe2+ have been eliminated and the conductivity suppressed), Fe3+ with the creation of 1/3VNd///. The switch in ionic compensation mechanism from 2/3VNd/// at low Ti concentrations (∼1%) to 1/3VNd/// at higher concentrations ( & gt;1%) results in a decrease in the magnitude of ΔTC/Δx, as the disruption of long range anti-polar coupling declines.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
2012
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
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