In:
Propellants, Explosives, Pyrotechnics, Wiley, Vol. 38, No. 6 ( 2013-12), p. 781-785
Abstract:
N‐heterocyclic compounds are key nitration precursors for some high energy density explosives such as 1,3,5,7‐tetranitro‐1,3,5,7‐tetraazacyclooctane (HMX). Nitration of 1,3,5,7‐tetraacetyl‐1,3,5,7‐tetraazacyclooctane (TAT) yields HMX in high yields and purity. However, the analogue 1,3,5‐triacetyl‐1,3,5‐triazacyclohexane (TRAT) is easily co‐produced via the condensation of acetonitrile and 1,3,5‐trioxan. To selectively extract TAT from a mixture of TAT and TRAT, the molecular imprinting technology (MIT) was developed in this study. The capacity of the dry polymer is 16 mg g −1 and the recovery surpasses 75 %.
Type of Medium:
Online Resource
ISSN:
0721-3115
,
1521-4087
DOI:
10.1002/prep.201300016
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
1481105-4
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