In:
Main Group Metal Chemistry, Walter de Gruyter GmbH, Vol. 41, No. 5-6 ( 2018-11-27), p. 155-160
Abstract:
Three bis(triorganotin) benzenedicarboxylates, 1, n -C 6 H 4 (COOSnR 3 ) 2 ( n , R=3, C 6 H 5 C(CH 3 ) 2 CH 2 , 1 ; 4, C 6 H 5 C(CH 3 ) 2 CH 2 , 2 ; 4, C 6 H 11 - c , 3 ), were synthesized by the reaction of 1,3 or 1,4-benzenedicarboxylic acid with triorganotin chlorides in the solution of CH 3 ONa-CH 3 OH and characterized by means of elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) ( 1 H, 13 C, and 119 Sn) spectra, and X-ray single-crystal diffraction. Compounds 1–3 are all di-nuclear tin complexes in which the carboxylate is monodentate and each tin atom possesses a distorted SnC 3 O tetrahedral geometry.
Type of Medium:
Online Resource
ISSN:
2191-0219
,
0792-1241
DOI:
10.1515/mgmc-2018-0031
Language:
Unknown
Publisher:
Walter de Gruyter GmbH
Publication Date:
2018
detail.hit.zdb_id:
2602433-0
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