In:
Particle & Particle Systems Characterization, Wiley, Vol. 31, No. 9 ( 2014-09), p. 1001-1007
Abstract:
Manganese oxide is a highly promising anode material of lithium‐ion batteries (LIBs) for its low insertion voltage and high reversible capacity. Porous MnO microspheres are prepared by a facile method in this work. As an anode material of LIB, it can deliver a high reversible capacity up to 1234.2 mA h g −1 after 300 cycles at 0.2 C, and a capacity of 690.0 mA h g −1 in the 500th cycle at 2 C. The capacity increase with cycling can be attributed to the growth of reversible polymer/gel‐like film, and the better cycling stability and the superior rate performance can be attributed to the featured structure of the microspheres composed of nanoparticles with a short transport path for lithium ions, a large specific surface, and material/electrolyte contact area. The results suggest that the porous MnO microspheres can function as a promising anode material for high‐performance LIBs.
Type of Medium:
Online Resource
ISSN:
0934-0866
,
1521-4117
DOI:
10.1002/ppsc.201400010
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
142874-3
detail.hit.zdb_id:
1481071-2
detail.hit.zdb_id:
246753-7
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