In:
Angewandte Chemie, Wiley, Vol. 132, No. 28 ( 2020-07-06), p. 11470-11474
Abstract:
Presented here is a class of novel axially chiral aryl‐ p ‐quinones as platform molecules for the preparation of non‐ C 2 symmetric biaryldiols. Two sets of aryl‐ p ‐quinone frameworks were synthesized with remarkable enantiocontrol by means of chiral phosphoric acid catalyzed enantioselective arylation of p ‐quinones by central‐to‐axial chirality conversion. These aryl‐ p ‐quinones were then used to access a wide spectrum of highly functionalized non‐ C 2 symmetric biaryldiols with excellent retention of the enantiopurity.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v132.28
DOI:
10.1002/ange.202004671
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
505868-5
detail.hit.zdb_id:
506609-8
detail.hit.zdb_id:
514305-6
detail.hit.zdb_id:
505872-7
detail.hit.zdb_id:
1479266-7
detail.hit.zdb_id:
505867-3
detail.hit.zdb_id:
506259-7
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