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  • 1
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2022
    In:  Nature Communications Vol. 13, No. 1 ( 2022-01-10)
    In: Nature Communications, Springer Science and Business Media LLC, Vol. 13, No. 1 ( 2022-01-10)
    Abstract: The subpolar Southern Ocean is a critical region where CO 2 outgassing influences the global mean air-sea CO 2 flux (F CO2 ). However, the processes controlling the outgassing remain elusive. We show, using a multi-glider dataset combining F CO2 and ocean turbulence, that the air-sea gradient of CO 2 (∆pCO 2 ) is modulated by synoptic storm-driven ocean variability (20 µatm, 1–10 days) through two processes. Ekman transport explains 60% of the variability, and entrainment drives strong episodic CO 2 outgassing events of 2–4 mol m −2 yr −1 . Extrapolation across the subpolar Southern Ocean using a process model shows how ocean fronts spatially modulate synoptic variability in ∆pCO 2 (6 µatm 2 average) and how spatial variations in stratification influence synoptic entrainment of deeper carbon into the mixed layer (3.5 mol m −2 yr −1 average). These results not only constrain aliased-driven uncertainties in F CO2 but also the effects of synoptic variability on slower seasonal or longer ocean physics-carbon dynamics.
    Type of Medium: Online Resource
    ISSN: 2041-1723
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 2553671-0
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  • 2
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2019
    In:  Global Biogeochemical Cycles Vol. 33, No. 10 ( 2019-10), p. 1204-1222
    In: Global Biogeochemical Cycles, American Geophysical Union (AGU), Vol. 33, No. 10 ( 2019-10), p. 1204-1222
    Abstract: Robust uncertainties for the recent change in the North Atlantic surface fCO 2 are determined by using observational‐based and model products The increasing North Atlantic surface fCO 2 is overestimated by ESMs during 1992–2014, and not captured by models' internal variability Simulation initialised with biogeochemical observations correct for the models' bias in the trend in surface CO 2 trends
    Type of Medium: Online Resource
    ISSN: 0886-6236 , 1944-9224
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2019
    detail.hit.zdb_id: 2021601-4
    SSG: 12
    SSG: 13
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  • 3
    In: Geoscientific Model Development, Copernicus GmbH, Vol. 12, No. 12 ( 2019-12-10), p. 5113-5136
    Abstract: Abstract. Over the last decade, advanced statistical inference and machine learning have been used to fill the gaps in sparse surface ocean CO2 measurements (Rödenbeck et al., 2015). The estimates from these methods have been used to constrain seasonal, interannual and decadal variability in sea–air CO2 fluxes and the drivers of these changes (Landschützer et al., 2015, 2016; Gregor et al., 2018). However, it is also becoming clear that these methods are converging towards a common bias and root mean square error (RMSE) boundary: “the wall”, which suggests that pCO2 estimates are now limited by both data gaps and scale-sensitive observations. Here, we analyse this problem by introducing a new gap-filling method, an ensemble average of six machine-learning models (CSIR-ML6 version 2019a, Council for Scientific and Industrial Research – Machine Learning ensemble with Six members), where each model is constructed with a two-step clustering-regression approach. The ensemble average is then statistically compared to well-established methods. The ensemble average, CSIR-ML6, has an RMSE of 17.16 µatm and bias of 0.89 µatm when compared to a test dataset kept separate from training procedures. However, when validating our estimates with independent datasets, we find that our method improves only incrementally on other gap-filling methods. We investigate the differences between the methods to understand the extent of the limitations of gap-filling estimates of pCO2. We show that disagreement between methods in the South Atlantic, southeastern Pacific and parts of the Southern Ocean is too large to interpret the interannual variability with confidence. We conclude that improvements in surface ocean pCO2 estimates will likely be incremental with the optimisation of gap-filling methods by (1) the inclusion of additional clustering and regression variables (e.g. eddy kinetic energy), (2) increasing the sampling resolution and (3) successfully incorporating pCO2 estimates from alternate platforms (e.g. floats, gliders) into existing machine-learning approaches.
    Type of Medium: Online Resource
    ISSN: 1991-9603
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
    detail.hit.zdb_id: 2456725-5
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