In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2003, No. 14 ( 2003-07), p. 2678-2682
Abstract:
Two novel zinc( II ) coordination polymers, [Zn 3 (μ 3 ‐OH) 2 (nip) 2 ] ( 1 ) and [Zn 2 (nip) 2 (4,4′‐bpy) 3 ·(OH 2 )] ( 2 ) (H 2 nip = 5‐nitroisophthalic acid, 4,4′‐bpy = 4,4′‐bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5‐nitroisophthalate (nip) (for 1 ) and zinc nitrate, 5‐nitroisophthalate and 4,4′‐bipyridyl (for 2 ). Complex 1 displays a two‐dimensional structure that is built from [Zn 3 (μ 3 ‐OH) 2 ] n chains, while complex 2 is a three‐dimensional structure formed by the interpenetration of two‐dimensional hydrogen‐bonded bilayers. The photoluminescent properties of complex 1 have also been investigated. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2003:14
DOI:
10.1002/ejic.200300021
Language:
English
Publisher:
Wiley
Publication Date:
2003
detail.hit.zdb_id:
1475009-0
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