In:
ChemCatChem, Wiley, Vol. 10, No. 11 ( 2018-06-07), p. 2378-2382
Abstract:
Highly activated, monodispersed N , N ‐dimethylformamide (DMF)‐stabilized iron‐oxide nanoparticles (Fe 2 O 3 NPs) were synthesized by using iron(III) acetylacetonate as a precursor under open‐air conditions. The resulting Fe 2 O 3 NPs were characterized by various techniques (e.g., transmission electron microscopy, dynamic light scattering, X‐ray diffraction, X‐ray photoelectron spectroscopy, FTIR spectroscopy, and X‐ray adsorption near‐edge structure). The Fe 2 O 3 NPs exhibited efficient catalytic activity for the hydrosilylation of alkenes without the need for further additives. An effective recycling process of the colloidal catalyst by extraction with a hexane/DMF system was developed, and recycling of the catalyst over five cycles did not result in any significant loss in catalytic activity.
Type of Medium:
Online Resource
ISSN:
1867-3880
,
1867-3899
DOI:
10.1002/cctc.201800161
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2501161-3
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