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  • 1
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2023
    In:  Clays and Clay Minerals Vol. 71, No. 5 ( 2023-10), p. 577-599
    In: Clays and Clay Minerals, Cambridge University Press (CUP), Vol. 71, No. 5 ( 2023-10), p. 577-599
    Abstract: Geologic repositories for spent nuclear fuel use bentonite as a buffer to protect the metallic containers confining the radioactive material. Sulfate-reducing bacteria, which may be present in groundwater, at the bentonite–host rock interface or eventually within the bentonite may produce sulfide, representing a potential threat for the metallic canisters, particularly copper. Bentonites can act as potential sulfide scavengers. Little is yet known, however, regarding the underlying mechanisms, the maximum extent of sulfide consumption, and the potential impacts on bentonite structure under repository conditions. In the current study, concentrated (4–150 mM) sulfide solutions were reacted in batch experiments with six natural Fe-bearing bentonites, with various purified Fe-bearing components of bentonite (a series of purified montmorillonites and three iron (oxyhydr)oxides), and with one synthetic mixture, for up to 1.5 months at pH values ranging from 7 to 13. The solutions were analyzed by colorimetry to determine sulfide and polysulfide concentrations and the solids were analyzed by 57 Fe Mössbauer spectrometry to determine iron speciation. Important sulfide consumption coupled with a reduction of structural Fe in the clay samples was observed. Not all clay structural Fe was reactive toward sulfide; the proportion of active structural Fe depended on the clay structure and pH. In the presence of excess sulfide in solution regarding Fe in the solid sample, the clay structural Fe was found to be the main reactant while the reaction with iron (oxyhydr)oxides was largely inhibited. Three bentonite groups were distinguished, based on the sulfide oxidation capacity of their main clayey component.
    Type of Medium: Online Resource
    ISSN: 0009-8604 , 1552-8367
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2023
    detail.hit.zdb_id: 2045991-9
    detail.hit.zdb_id: 221428-3
    SSG: 13
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  • 2
    In: Applied Geochemistry, Elsevier BV, Vol. 138 ( 2022-03), p. 105205-
    Type of Medium: Online Resource
    ISSN: 0883-2927
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2022
    detail.hit.zdb_id: 1499242-5
    SSG: 13
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  • 3
    In: Materials and Corrosion, Wiley
    Abstract: Posiva Oy have submitted an operating licence application to the Finnish government which, if approved, would permit the disposal of spent fuel in a deep geological repository at Olkiluoto. The license application is based on 40 years of site investigations, design and development work by Finnish, Swedish, and international experts. The canister is a key component of the overall multi‐barrier system and the treatment of the long‐term corrosion performance in the safety case is described in this paper. The importance of relating laboratory observations to the expected environmental conditions in the repository is highlighted, as is the use of complementary models to build confidence in long‐term predictions. Canister lifetime prediction is based on a combination of corrosion allowances for processes that will occur to a limited extent and mass‐transport calculations for the long‐term corrosion by sulphide. Examples of canister lifetime predictions for various scenarios and climate lines of evolution are given.
    Type of Medium: Online Resource
    ISSN: 0947-5117 , 1521-4176
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 1481051-7
    detail.hit.zdb_id: 1224916-6
    detail.hit.zdb_id: 202688-0
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  • 4
    In: Informaatiotutkimus, Informaatiotutkimus, Vol. 40, No. 3 ( 2021-11-05)
    Abstract: Semanttinen parlamentti -hankkeessa 2020–2022 luodaan eduskunnan tietokannoista ja niihin liittyvistä muista aineistoista uudenlainen linkitetyn avoimen datan (Linked Open Data, LOD) palvelu, tietoinfrastruktuuri ja semanttinen portaali Parlamenttisampo – eduskunta semant­tisessa webissä, joiden avulla tutkitaan poliittista kulttuuria ja kieltä. Dataa linkittämällä voi-daan rikastaa eduskuntadataa muilla tietolähteillä kuten biografisella tiedolla, terminologioilla ja lainsäädännön dokumenteilla. Parlamenttisampo on kieli- ja semanttisen webin teknologioihin perustuva palvelukokonaisuus tutkijoita, kansalaisia, mediaa ja valtionhallintoa varten. Artik­kelissa esitellään hankkeen visio, ensimmäisiä tuloksia ja niiden hyödyntämismahdollisuuksia: Eduskunnan kaikkien täysistuntojen 1907–2021 yli 900 000 puheesta on valmistunut linkitetyn datan tietämysgraafi (knowledge graph); data on myös saatavilla XML-muodossa, jossa hyö­dynnetään uutta kansainvälistä Parla-CLARIN-formaattia. Ensimmäistä kertaa eduskunnan puheiden koko aikasarja on muunnettu dataksi ja datapalveluksi yhtenäisessä muodossa. Lisäksi puheet on yhdistetty eduskunnan kansanedustajien tietokannasta luotuun ja muista tietolähteistä rikastettuun toiseen tietämysgraafiin laajemmaksi ontologiaperustaiseksi datapalveluksi Fin- Parla. Datapalvelua voidaan käyttää eduskuntatutkimukseen parlamentaarisesta ja edustuksel-lisesta kulttuurista sekä poliittisen kielen käytöstä analysoimalla kansanedustajien täysistunnois­sa pitämiä puheita ja poliitikkojen verkostoja data-analyysin keinoin. Palvelun rajapinnan avulla voidaan myös kehittää eri käyttäjäryhmille sovelluksia, kuten hankkeessa valmistuva Parlament­tisampo.fi-portaali.
    Type of Medium: Online Resource
    ISSN: 1797-9129 , 1797-9137
    Language: Unknown
    Publisher: Informaatiotutkimus
    Publication Date: 2021
    detail.hit.zdb_id: 2592246-4
    SSG: 24,1
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  • 5
    In: Semantic Web, IOS Press, Vol. 12, No. 2 ( 2021-01-26), p. 265-278
    Abstract: The Second World War (WW2) is arguably the most devastating catastrophe of human history, a topic of great interest to not only researchers but the general public. However, data about the Second World War is heterogeneous and distributed in various organizations and countries making it hard to utilize. In order to create aggregated global views of the war, a shared ontology and data infrastructure is needed to harmonize information in various data silos. This makes it possible to share data between publishers and application developers, to support data analysis in Digital Humanities research, and to develop data-driven intelligent applications. As a first step towards these goals, this article presents the WarSampo knowledge graph (KG), a shared semantic infrastructure, and a Linked Open Data (LOD) service for publishing data about WW2, with a focus on Finnish military history. The shared semantic infrastructure is based on the idea of representing war as a spatio-temporal sequence of events that soldiers, military units, and other actors participate in. The used metadata schema is an extension of CIDOC CRM, supplemented by various military history domain ontologies. With an infrastructure containing shared ontologies, maintaining the interlinked data brings upon new challenges, as one change in an ontology can propagate across several datasets that use it. To support sustainability, a repeatable automatic data transformation and linking pipeline has been created for rebuilding the whole WarSampo KG from the individual source datasets. The WarSampo KG is hosted on a data service based on W3C Semantic Web standards and best practices, including content negotiation, SPARQL API, download, automatic documentation, and other services supporting the reuse of the data. The WarSampo KG, a part of the international LOD Cloud and totalling ca. 14 million triples, is in use in nine end-user application views of the WarSampo portal, which has had over 690 000 end users since its opening in 2015.
    Type of Medium: Online Resource
    ISSN: 2210-4968 , 1570-0844
    Language: Unknown
    Publisher: IOS Press
    Publication Date: 2021
    detail.hit.zdb_id: 2599324-0
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