In:
Angewandte Chemie International Edition, Wiley, Vol. 48, No. 11 ( 2009-03-02), p. 2012-2016
Abstract:
In close quarters : When confined in a metal–organic framework, magnesium borohydride reacts with arenes by a hydroboration pathway (see scheme), in contrast to its reactivity under analogous homogeneous solution‐phase conditions. Framework‐imposed organization of the reactive groups is required, which is achieved by a combination of the metal coordination and two hydrogen bonds. magnified image
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.200804196
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7
Permalink