In:
The Journal of Chemical Physics, AIP Publishing, Vol. 113, No. 13 ( 2000-10-01), p. 5361-5371
Abstract:
We have determined photodissociation spectra of Ag4+(N2)m=0–4 in the photon energy range from 2.1 to 3.75 eV. The cluster complexes were generated by laser vaporization and their absolute photodissociation cross sections were measured in depletion using a modified reflectron time-of-flight mass spectrometer. The band spectra show significant nonmonotonic variations with increasing N2 coverage. The experimental data are contrasted with quantum chemical calculations of ground and electronically excited states using density functional as well as post-Hartree–Fock methods. Experiment and theory are in qualitative agreement allowing tentative assignment of the depletion spectra and insight into the relevant bonding interactions.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
2000
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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