In:
Applied Physics Letters, AIP Publishing, Vol. 72, No. 21 ( 1998-05-25), p. 2648-2650
Abstract:
We report on the demonstration of the femtosecond nonlinear optical response from a two-dimensional monomolecular layer of squarylium dye J aggregate at 5 °C. The formation of a monomolecular layer Langmuir film was achieved by spreading squarylium dye modified by two propyl and two hexyl groups at the air–water interface, which resulted in a very strong J band (o.d.=0.3) at 777 nm. The transient absorption spectra in a resonant pump-probe measurement showed a low absorption saturation power (9.7×106 W/cm2) and an ultrafast response (300 fs), which are indicative of exciton delocalization over 18 molecules in this J aggregate, even at 5 °C.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
1998
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
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