In:
Molecules, MDPI AG, Vol. 25, No. 13 ( 2020-07-03), p. 3055-
Abstract:
New metal-organic frameworks (MOF) with lanthanum(III), cerium(III), neodymium(III), europium(III), gadolinium(III), dysprosium(III), and holmium(III)] and the ligand precursor 1,3,5-tris(4-carboxyphenyl)-2,4,6-trimethylbenzene (H3L) were synthesized under solvothermal conditions. Single crystal x-ray analysis confirmed the formation of three-dimensional frameworks of [LnL(H2O)2] n·xDMF·yH2O for Ln = La, Ce, and Nd. From the nitrogen sorption experiments, the compounds showed permanent porosity with Brunauer-Emmett-Teller (BET) surface areas of about 400 m2/g, and thermal stability up to 500 °C. Further investigations showed that these Ln-MOFs exhibit catalytic activity, paving the way for potential applications within the field of catalysis.
Type of Medium:
Online Resource
ISSN:
1420-3049
DOI:
10.3390/molecules25133055
Language:
English
Publisher:
MDPI AG
Publication Date:
2020
detail.hit.zdb_id:
2008644-1
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