In:
Propellants, Explosives, Pyrotechnics, Wiley, Vol. 36, No. 3 ( 2011-06), p. 219-224
Abstract:
The existence of two new types of chloroderivates of cyclic acetone peroxides – 3‐(chloromethyl)‐3,6,6,9,9‐pentamethyl‐1,2,4,5,7,8‐hexoxonane and 3,6‐ bis (chloromethyl)‐3,6,9,9‐tetramethyl‐1,2,4,5,7,8‐hexoxonane was proved by HPLC/MS/MS and NMR in the reaction products when acetone and hydrogen peroxide are mixed in the presence of excess hydrochloric acid (molar ratio hydrochloric acid to acetone n c / n a =2.5). The details of analysis, and the conditions under which these asymmetric chloroderivates of cyclic peroxides form, are described.
Type of Medium:
Online Resource
ISSN:
0721-3115
,
1521-4087
DOI:
10.1002/prep.201000158
Language:
English
Publisher:
Wiley
Publication Date:
2011
detail.hit.zdb_id:
1481105-4
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