In:
Angewandte Chemie International Edition, Wiley, Vol. 56, No. 25 ( 2017-06-12), p. 7056-7061
Abstract:
Intramolecular atropselective aza Paternò–Büchi reaction involving atropisomeric enamide and imine functionalities under sensitized irradiation leads to azetidine products in good yield and selectivity ( ee 〉 96 %). A mechanistic model based on detailed photophysical and isomerization kinetic studies is provided that shed light into the reactivity of enamides leading to aza Paternò–Büchi reaction.
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.201702273
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7
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