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  • 1
    In: The Astrophysical Journal, American Astronomical Society, Vol. 939, No. 2 ( 2022-11-01), p. 122-
    Abstract: Observations of CH + are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH + chemistry. Until this work, the most uncertain reaction in that chemistry was dissociative recombination (DR) of CH + . Using an electron–ion merged-beams experiment at the Cryogenic Storage Ring, we have determined the DR rate coefficient of the CH + electronic, vibrational, and rotational ground state applicable for different diffuse cloud conditions. Our results reduce the previously unrecognized order-of-magnitude uncertainty in the CH + DR rate coefficient to ∼20% and are applicable at all temperatures relevant to diffuse clouds, ranging from quiescent gas to gas locally heated by processes such as shocks and turbulence. Based on a simple chemical network, we find that DR can be an important destruction mechanism at temperatures relevant to quiescent gas. As the temperature increases locally, DR can continue to be important up to temperatures of ∼600 K, if there is also a corresponding increase in the electron fraction of the gas. Our new CH + DR rate-coefficient data will increase the reliability of future studies of diffuse cloud physical properties via CH + abundance observations.
    Type of Medium: Online Resource
    ISSN: 0004-637X , 1538-4357
    RVK:
    Language: Unknown
    Publisher: American Astronomical Society
    Publication Date: 2022
    detail.hit.zdb_id: 2207648-7
    detail.hit.zdb_id: 1473835-1
    SSG: 16,12
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  • 2
    In: The Astrophysical Journal Letters, American Astronomical Society, Vol. 955, No. 2 ( 2023-10-01), p. L26-
    Abstract: Observations of OH + are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy cosmic ray spectrum. In regions where the H 2 -to-H number density ratio is low, dissociative recombination (DR) is the dominant destruction process for OH + and the DR rate coefficient is important for predicting the OH + abundance and inferring the cosmic ray ionization rate. We have experimentally studied DR of electronically and vibrationally relaxed OH + in its lowest rotational levels, using an electron–ion merged-beams setup at the Cryogenic Storage Ring. From these measurements, we have derived a kinetic temperature rate coefficient applicable to diffuse cloud chemical models, i.e., for OH + in its electronic, vibrational, and rotational ground level. At typical diffuse cloud temperatures, our kinetic temperature rate coefficient is a factor of ∼5 times larger than the previous experimentally derived value and a factor of ∼33 times larger than the value calculated by theory. Our combined experimental and modeling results point to a significant increase for the cosmic ray ionization rate inferred from observations of OH + and H 2 O + , corresponding to a geometric mean of (6.6 ± 1.0) × 10 −16 s −1 , which is more than a factor of 2 larger than the previously inferred values of the cosmic ray ionization rate in diffuse atomic clouds. Combined with observations of diffuse and dense molecular clouds, these findings indicate a greater degree of cosmic ray shielding in interstellar clouds than has been previously inferred.
    Type of Medium: Online Resource
    ISSN: 2041-8205 , 2041-8213
    Language: Unknown
    Publisher: American Astronomical Society
    Publication Date: 2023
    detail.hit.zdb_id: 2207648-7
    detail.hit.zdb_id: 2006858-X
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  • 3
    Online Resource
    Online Resource
    IOP Publishing ; 2021
    In:  Journal of Physics B: Atomic, Molecular and Optical Physics Vol. 54, No. 5 ( 2021-03-03), p. 055701-
    In: Journal of Physics B: Atomic, Molecular and Optical Physics, IOP Publishing, Vol. 54, No. 5 ( 2021-03-03), p. 055701-
    Abstract: Tunable diode laser induced fluorescence (TDLIF) measurements are discussed and quantitatively evaluated for nitrogen admixtures in argon plasma under the influence of a strong magnetic field. TDLIF measurements were used to evaluate light-transport properties in a strongly magnetized optically thick argon/nitrogen plasma under different pressure conditions. Therefore, a coupled system of rate balance equations was constructed to describe laser pumping of individual magnetic sub-levels of 2p 8 state through frequency-separated sub-transitions originating from 1s 4 magnetic sub-levels. The density distribution (alignment) of 2p 8 multiplet was described by balancing laser pumping with losses including radiative decay, transfer of excitation between the neighboring sub-levels in the 2p 8 multiplet driven by neutral collisions (argon and nitrogen) and quenching due to electron and neutral collisions. Resulting 2p 8 magnetic sub-level densities were then used to model polarization dependent fluorescence, considering self-absorption, which could be directly compared with polarization-resolved TDLIF measurements. This enables to estimate the disalignment rate constant for the 2p 8 state due to collisions by molecular nitrogen. A comparison to molecular theory description is given providing satisfactory agreement. The presented measurement method and model can help to describe optical emission of argon and argon–nitrogen admixtures in magnetized conditions and provides a basis for further description of optical emission spectra in magnetized plasmas.
    Type of Medium: Online Resource
    ISSN: 0953-4075 , 1361-6455
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 3111439-8
    detail.hit.zdb_id: 209218-9
    detail.hit.zdb_id: 1363381-8
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  • 4
    Online Resource
    Online Resource
    Institute of Electrical and Electronics Engineers (IEEE) ; 2018
    In:  IEEE Transactions on Plasma Science Vol. 46, No. 2 ( 2018-2), p. 214-218
    In: IEEE Transactions on Plasma Science, Institute of Electrical and Electronics Engineers (IEEE), Vol. 46, No. 2 ( 2018-2), p. 214-218
    Type of Medium: Online Resource
    ISSN: 0093-3813 , 1939-9375
    Language: Unknown
    Publisher: Institute of Electrical and Electronics Engineers (IEEE)
    Publication Date: 2018
    detail.hit.zdb_id: 2025402-7
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  • 5
    Online Resource
    Online Resource
    AIP Publishing ; 2021
    In:  Physics of Plasmas Vol. 28, No. 1 ( 2021-01-01)
    In: Physics of Plasmas, AIP Publishing, Vol. 28, No. 1 ( 2021-01-01)
    Abstract: A new quantitative evaluation of tunable diode laser induced fluorescence (TDLIF) measurements in magnetized plasma is presented in this article, taking into account Zeeman splitting of energetic levels as well as inter- and intra-multiplet mixing, defining the density distribution (alignment) of the excited 2p8 multiplet of argon. TDLIF measurements were used to evaluate light-transport properties in a strongly magnetized optically thick argon plasma under different pressure conditions. Therefore, a coupled system of rate balance equations was constructed to describe laser pumping of individual magnetic sub-levels of the 2p8 state through frequency-separated sub-transitions originating from 1s4 magnetic sub-levels. The density distribution of the 2p8 multiplet was described by balancing laser pumping with losses, including radiative decay, transfer of excitation between the neighboring levels within the 2p8 multiplet driven by neutral collisions, and quenching due to electron and neutral collisions. Resulting 2p8 magnetic sub-level densities were then used to model polarization dependent fluorescence, considering self-absorption, which could be directly compared with measured polarization-resolved TDLIF measurements. The achieved results enable to obtain unique solutions for the 1s4 and 1s5 magnetic sub-level densities which were found to be in good agreement with the densities obtained by laser absorption measurements. It is shown that polarization resolved TDLIF measurements in magnetized plasma conditions have strong pressure dependence. The effective disalignment rate constant which redistributes the 2p8 sub-levels among each other has to be considered for a correct description of the TDLIF. This rate is dependent on the neutral gas density and a specific rate coefficient. With the presented method, 1s state densities involved in the TDLIF can be determined without any absolute intensity calibration in an optically thick plasma. Additionally, the presented measurement method and model can help to further understand and improve the description of optical emission of argon based on individual sub-transition descriptions under magnetized conditions.
    Type of Medium: Online Resource
    ISSN: 1070-664X , 1089-7674
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 1472746-8
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