In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 37, No. 11 ( 1982-11-1), p. 1456-1460
Abstract:
Triorganotin and -lead derivatives of X-benzoylglveine (BzGlyH) and N-formylglycine (ForGlyH), R 3 MBzGly and R 3 MForGly (M = Sn; R = Me, Ph. M = Pb; R = Ph) have been prepared from R 3 MOH and BzGlyH or ForGlyH, respectively. According to spectroscopic data the Me 3 Sn groups are essentially planar; molecules of R 3 SnForGly are bridged by unidentate carboxylate groups and formyl-C = O groups in the solid state, while Ph 3 PbForGly and benzoylglycinates are bridged by bidentate carboxylate groups. NH does not coordinate to M. Pentacoordination and a polymeric nature in the solid state is also indicated by Mößbauer data of Me 3 SnForGly and Me 3 SnBzGly. In solution all compounds are monomeric.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1982-1118
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1982
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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