In:
Collection of Czechoslovak Chemical Communications, Institute of Organic Chemistry & Biochemistry, Vol. 57, No. 5 ( 1992), p. 969-977
Abstract:
Hydrocracking of n-hexane and diesel oil fraction over presulfided NiMo, Mo and Ni catalysts has been carried out using a high pressure flow reactor system. The ion-exchanged form of ZSM-5 extrudates (50% alumina binder) was loaded with 2-20 wt.% of metals. The results indicate that, using Ni/H-ZSM-5 zeolite obtained by incorporation of nickel by ion exchange treatment of NH 4 -ZSM-5 from nickel nitrate solution, it is possible to obtain sufficiently active catalysts for low-temperature hydrocracking process. The catalysts containing Ni-ZSM-5 zeolites (Ni/H-ZSM-5 or Ni/Na-ZSM-5) were superior to catalyst prepared by using P/H-ZSM-5. It was found that nickel was an essential hydrogenation components of low temperature hydrocracking catalysts.
Type of Medium:
Online Resource
ISSN:
0010-0765
,
1212-6950
DOI:
10.1135/cccc19920969
Language:
English
Publisher:
Institute of Organic Chemistry & Biochemistry
Publication Date:
1992
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