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  • 1
    Online Resource
    Online Resource
    Bulletin Mineralogie Petrologie ; 2021
    In:  Bulletin Mineralogie Petrologie Vol. 29, No. 2 ( 2021), p. 241-248
    In: Bulletin Mineralogie Petrologie, Bulletin Mineralogie Petrologie, Vol. 29, No. 2 ( 2021), p. 241-248
    Abstract: The zýkaite samples were found at abandoned Lehnschafter mine near Mikulov in the Krušné hory Mts. (Czech Republic). It occurs as irregular white to light greenish rounded to spherical aggregates up to 1.5 cm in size composed of tiny acicular crystals up to 5 - 10 μm in length. Its empirical formula can be expressed as (Fe3.79Al0.02)Σ3.81[(AsO4)2.66(PO4)0.20(SiO4)0.07]Σ2.93 (SO4)1.07(OH)0.44·15H2O (mean of 3 spot analyzes; on the basis of As+P+S+Si = 4 apfu).Zýkaite is probably monoclinic, with the unit-cell parameters refined from X-ray powder diffraction data: a 21.195(8), b 7.052(2), c 36.518(17) Å, β 91.07(2)° and V 5458(2) Å3. Raman spectroscopy documented the presence of both (AsO4)3- and (SO4)2- units in the crystal structure of zýkaite. Multiple Raman bands connected with vibrations of water molecules and (AsO4)3- groups indicate the presence of more structurally non-equivalent these groups in the crystal stucture of zýkaite.
    Type of Medium: Online Resource
    ISSN: 2570-7345 , 2570-7337
    URL: Issue
    Language: cs
    Publisher: Bulletin Mineralogie Petrologie
    Publication Date: 2021
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  • 2
    Online Resource
    Online Resource
    Bulletin Mineralogie Petrologie ; 2020
    In:  Bulletin Mineralogie Petrologie Vol. 28, No. 2 ( 2020), p. 385-405
    In: Bulletin Mineralogie Petrologie, Bulletin Mineralogie Petrologie, Vol. 28, No. 2 ( 2020), p. 385-405
    Abstract: An extraordinary rich mineral assemblage consisting of 27 minerals has been newly discovered in quartz veins of the abandoned ore deposit, once exploited by the Drei König Mine, called also Giftschacht (Jedová jáma - Toxic shaft), situated approximately 2 km SE of Vejprty town. It includes 16 sulphides (plus one unnamed) with far prevailing arsenopyrite. In addition to common sulphides (chalcopyrite, sphalerite, galena and minerals of the tetrahedrite group), a wide suite of sulphosalts with substantial Bi-content was identified. Besides common bismuthinite and emplectite, also relatively rare Bi minerals (matildite, aikinite, hammarite, wittichenite), in the Czech Republic known from few localities only, have been found here. Bi is bound also in a rather exotic selenide bohdanowitzite and native bismuth. Bi is substantially present in some domains of tetrahedrites [tetrahedrite-(Zn), tennantite-(Zn) and tennantite-(Fe)]. In addition to local Bi enrichment, also Sn-minerals occur in the ore, represented by cassiterite and rare sulphides (kësterite and stannoidite). The presence of phosphates of the plumbogummite group [plumbogummite, goyazite and florencite-(Ce)] contributes to the remarkable mineral assemblage. From geochemical point of view, very interesting is the presence of florencite-(Ce), in which REE with dominating Ce are fixed. In addition, grains of fluorite, fluorapatite, rutile, topaz and aggregates of illite and a phase from kaolinite group are present. Supergene mineralization is represented besides limonite by abundant scorodite and rare strengite.
    Type of Medium: Online Resource
    ISSN: 2570-7345 , 2570-7337
    URL: Issue
    Language: cs
    Publisher: Bulletin Mineralogie Petrologie
    Publication Date: 2020
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  • 3
    Online Resource
    Online Resource
    Bulletin Mineralogie Petrologie ; 2020
    In:  Bulletin Mineralogie Petrologie Vol. 28, No. 1 ( 2020), p. 48-57
    In: Bulletin Mineralogie Petrologie, Bulletin Mineralogie Petrologie, Vol. 28, No. 1 ( 2020), p. 48-57
    Abstract: Two rare sulfosalt minerals, fülöppite and plagionite, have been determined in samples from a small abandoned Sb occurrence Mikulovický vrch near Kadaň, northern Bohemia, Czech Republic. The more abundant fülöppite forms grey aggregates (up to 5 mm in size) with metallic lustre in quartz gangue and rare crystals up to 1.5 mm across in association with stibnite, plagionite, sphalerite, pyrite and arsenopyrite. Fülöppite is monoclinic, space group C2/c with refined unit-cell parameters: a 13.443(2), b 11.737(2), c 16.953(2) Å, β 94.69(1)° and V 2665.9(5) Å3. Its empirical formula (mean of 93 point analyses) is (Pb2.80Sn0.01Hg0.01)Σ2.82Sb8.18S14.99. Two types of plagionite were found as irregular aggregates up to 200 μm in size in quartz gangue, ussualy in association with fülöppite. The first rarer one is close to the ideal composition with empirical formula (mean of 10 point analyses) (Pb4.90Hg0.01)Σ4.91Sb8.07S17.02; the second is distinctly Pb-poor with the calculated N homologue number in the range of 1.37 - 1.74 and empirical formula (mean of 62 point analyses) (Pb4.31Sn0.02Hg0.01)Σ4.34Sb8.53S17.13. Determination of fülöppite and Pb-poor plagionite were also confirmed by Raman spectroscopy. Gypsum, valentinite, native sulphur and jarosite were detected as products of weathering of primary mineralization.
    Type of Medium: Online Resource
    ISSN: 2570-7345 , 2570-7337
    URL: Issue
    Language: cs
    Publisher: Bulletin Mineralogie Petrologie
    Publication Date: 2020
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  • 4
    In: Bulletin Mineralogie Petrologie, Bulletin Mineralogie Petrologie, Vol. 28, No. 1 ( 2020), p. 170-178
    Abstract: Supergene Bi mineralization with namibite, bismutoferrite and bismutite was found on a quartz-fluorite vein Nadějná near the Kotlina in the Krušné hory Mts. (Czech Republic). Namibite forms green coatings on the cracks of fluorite veins and more rarely dark green glassy lustrous, hedgehog-shaped aggregates up to 0.2 mm in size formed by flat needle-like crystals. The unit-cell parameters of namibite refined from the powder X-ray data are: a 6.2096(18), b 7.395(2), c 7.4708(18) Å, α 90.1(2)°, β 108.73(15)°, γ 107.45(19)° and V 308.09(15) Å3. Its chemical analyses correspond to the empirical formula (Cu0.93Fe0.03Ca0.01)Σ0.97(BiO)1.79(V0.97P0.02Cr0.01)Σ1.00O4(OH)0.75. Bismutoferrite forms yellow powdery aggregates in cracks and in small cavities of fluorite. Its chemical analyses correspond to the empirical formula (Fe1.91 Cu0.03Mg0.02Al0.02Ca0.01)Σ1.99Bi0.92(SiO4)2.00(OH)0.68. Bismutite in the fluorite vein forms yellow-white pseudomorphoses probably after the acicular crystals of primary Bi sulfide (emplectite or bismuthinite) up to 2 mm long. Study of Raman spectra was performed for all studied minerals.
    Type of Medium: Online Resource
    ISSN: 2570-7345 , 2570-7337
    URL: Issue
    Language: cs
    Publisher: Bulletin Mineralogie Petrologie
    Publication Date: 2020
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  • 5
    Online Resource
    Online Resource
    Bulletin Mineralogie Petrologie ; 2021
    In:  Bulletin Mineralogie Petrologie Vol. 29, No. 2 ( 2021), p. 351-368
    In: Bulletin Mineralogie Petrologie, Bulletin Mineralogie Petrologie, Vol. 29, No. 2 ( 2021), p. 351-368
    Abstract: An interesting copper mineralization has been discovered in fragments of hydrothermal quartz gangue found in dump material of the abandoned unnamed gallery 1.5 km S from Horní Halže (now part of the Měděnec village), the Krušné hory Mts., Czech Republic. The primary mineralization represented by fine-grained quartz, hematite, pyrite and probably also djurleite was intensively affected by supergene processes. Djurleite and pyrite are partly replaced by Cu sulphides - roxbyite, anilite, spionkopite and covellite. The origin of association bornite/half-bornite/anilite found in some samples can be analogous, although in this case it cannot be ruled out that it may be the result of decomposition of the original solid solution (against the ideal bornite clearly enriched in Cu) formed in the hydrothermal stage. The formation of other Cu minerals (malachite, brochantite, libethenite and pseudomalachite) and goethite is already clearly bound to supergene conditions, part of malachite and brochantite was then formed by (sub)recent weathering of Cu-sulphides in the mine dump material. The detailed descriptions, X-ray powder diffraction data, refined unit-cell parameters and quantitative chemical composition of individual studied mineral phases are presented.
    Type of Medium: Online Resource
    ISSN: 2570-7345 , 2570-7337
    URL: Issue
    Language: cs
    Publisher: Bulletin Mineralogie Petrologie
    Publication Date: 2021
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