In:
Journal of the Chinese Chemical Society, Wiley, Vol. 65, No. 3 ( 2018-03), p. 312-316
Abstract:
A method providing expeditious access to chiral allylic amines via a Rh(I)/bicyclo[2.2.1]heptadiene‐catalyzed enantioselective alkenylation of N ‐tosyl aldimines with potassium alkenyltrifluoroborates under microwave irradiation is described. The rate of the asymmetric 1,2‐addition reaction, conducted in the presence of 1 mol % of the catalyst, was significantly enhanced as compared to when the standard heating method was applied while still providing the corresponding products without decrease in enantioselectivity.
Type of Medium:
Online Resource
ISSN:
0009-4536
,
2192-6549
DOI:
10.1002/jccs.2018.65.issue-3
DOI:
10.1002/jccs.201600888
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2029538-8
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