In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 59, No. 49 ( 2023), p. 7627-7630
Abstract:
A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
1472881-3
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