In:
Доклады Академии наук, The Russian Academy of Sciences, Vol. 489, No. 4 ( 2019-12-10), p. 368-372
Abstract:
N‑heterocyclic phospholes based on N,N-disubstituted 9,10-phenanthrenediimines were synthesized. Dimeric 1,3,2-diazaphospholes were obtained by reduction of 2-bromo diazaphospholes. In case phenanthrediimine with the most sterically hindrance, diphosphole can dissociate into phosphorus-centered radicals at record low temperatures (220 K) for this class. This behavior will allow the synthesis of new metal complexes and phosphorus-organic compounds under mild conditions.
Type of Medium:
Online Resource
ISSN:
0869-5652
DOI:
10.31857/S0869-56524894
DOI:
10.31857/S0869-56524894368-372
Language:
Unknown
Publisher:
The Russian Academy of Sciences
Publication Date:
2019
detail.hit.zdb_id:
1109534-9
detail.hit.zdb_id:
3019980-3
SSG:
11
Permalink