In:
Angewandte Chemie, Wiley, Vol. 135, No. 10 ( 2023-03)
Abstract:
We report phosphinidenes (PR) stabilized by an intramolecular frustrated Lewis pair (FLP) chelate. These adducts include the parent phosphinidene, PH, which is accessed via thermolysis of coordinated HPCO. The reported FLP‐PH species acts as a springboard to other phosphorus‐containing compounds, such as FLP‐adducts of diphosphorus (P 2 ) and InP 3 . Our new adducts participate in thermal‐ or light‐induced phosphinidene elimination (of both PH and PR, R=organic group), transfer P 2 units to an organic substrate, and yield the useful semiconductor InP at only 110 °C from solution.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v135.10
DOI:
10.1002/ange.202218587
Language:
English
Publisher:
Wiley
Publication Date:
2023
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