In:
Applied Physics Letters, AIP Publishing, Vol. 99, No. 13 ( 2011-09-26)
Abstract:
We have investigated the electronic structure of ZnO:Mn and ZnO:Mn,N thin films using x-ray magnetic circular dichroism (XMCD) and resonance-photoemission spectroscopy. From the Mn 2p → 3d XMCD results, it is shown that, while XMCD signals only due to paramagnetic Mn2+ ions were observed in ZnO:Mn, nonmagnetic, paramagnetic, and ferromagnetic Mn2+ ions coexist in ZnO:Mn,N. XMCD signals of ZnO:Mn,N revealed that the localized Mn2+ ground state and Mn2+ state hybridized with ligand hole coexisted, implying p-d exchange coupling. In the valence-band spectra, spectral weight near the Fermi level was suppressed, suggesting that interaction between magnetic moments in ZnO:Mn,N has localized nature.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
2011
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
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