In:
Chemistry – A European Journal, Wiley, Vol. 28, No. 62 ( 2022-11-07)
Abstract:
Non‐metal nitrides are an exciting field of chemistry, featuring a significant number of compounds that can possess outstanding material properties. These properties mainly rely on maximizing the number of strong covalent bonds, with crosslinked XN 6 octahedra frameworks being particularly attractive. In this study, the phosphorus–nitrogen system was studied up to 137 GPa in laser‐heated diamond anvil cells, and three previously unobserved phases were synthesized and characterized by single‐crystal X‐ray diffraction, Raman spectroscopy measurements and density functional theory calculations. δ‐P 3 N 5 and PN 2 were found to form at 72 and 134 GPa, respectively, and both feature dense 3D networks of the so far elusive PN 6 units. The two compounds are ultra‐incompressible, having a bulk modulus of K 0 =322 GPa for δ‐P 3 N 5 and 339 GPa for PN 2 . Upon decompression below 7 GPa, δ‐P 3 N 5 undergoes a transformation into a novel α′‐P 3 N 5 solid, stable at ambient conditions, that has a unique structure type based on PN 4 tetrahedra. The formation of α′‐P 3 N 5 underlines that a phase space otherwise inaccessible can be explored through materials formed under high pressure.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.202201998
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
1478547-X
Permalink